Surface Recombination of H Atoms on Pyrex in Medium-Pressure Hydrogen Plasma

IF 1.1 4区 物理与天体物理 Q4 PHYSICS, FLUIDS & PLASMAS
I. I. Ziganshin, K. R. Galiullin, D. V. Lopaev, E. A. Kirillov, A. T. Rakhimov
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Abstract

The probability of heterogeneous recombination of hydrogen atoms, γH, on the surface of a Pyrex tube in a direct current glow discharge in pure hydrogen at medium pressure (2–7 Torr) has been measured as a function of the discharge pressure and current for two wall temperatures. It has been found that the recombination probability does not depend on the discharge pressure and current under the condition of preliminary training of the tube in a hydrogen discharge. The γH value decreases during the tube training with a characteristic time of reaching a steady-state value of ~30 min. Analysis of a possible recombination mechanism using quantum chemical methods shows that the recombination of hydrogen atoms on the Pyrex surface is associated with OH radicals and oxygen vacancies on the surface, and the dynamics of γH can be explained by the decay of surface OH radicals during tube training.

Abstract Image

中压氢等离子体中高温热石中H原子的表面复合
用纯氢在中压(2-7 Torr)下进行直流辉光放电,测定了在两种壁温下,Pyrex管表面氢原子γH非均相复合的概率与放电压力和电流的关系。研究发现,在氢气放电中对管进行初步训练的情况下,复合概率与放电压力和电流无关。在管式训练过程中,γ - h值呈下降趋势,特征时间为~ 30min。利用量子化学方法对可能的重组机制进行了分析,结果表明,Pyrex表面氢原子的重组与表面OH自由基和氧空位有关,而γ - h的动力学可以用管训练过程中表面OH自由基的衰减来解释。
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来源期刊
Plasma Physics Reports
Plasma Physics Reports 物理-物理:流体与等离子体
CiteScore
1.90
自引率
36.40%
发文量
104
审稿时长
4-8 weeks
期刊介绍: Plasma Physics Reports is a peer reviewed journal devoted to plasma physics. The journal covers the following topics: high-temperature plasma physics related to the problem of controlled nuclear fusion based on magnetic and inertial confinement; physics of cosmic plasma, including magnetosphere plasma, sun and stellar plasma, etc.; gas discharge plasma and plasma generated by laser and particle beams. The journal also publishes papers on such related topics as plasma electronics, generation of radiation in plasma, and plasma diagnostics. As well as other original communications, the journal publishes topical reviews and conference proceedings.
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