Binary Acidic/Alkaline Aqueous Electrolytes

IF 1.3 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY
V. Shikin
{"title":"Binary Acidic/Alkaline Aqueous Electrolytes","authors":"V. Shikin","doi":"10.1134/S002136402560627X","DOIUrl":null,"url":null,"abstract":"<p>The properties of dilute, compensated “weak” electrolytes on the example of the binary mixture “acid + alkali + water” have been discussed within the framework of phenomenological energy statistics. The concepts of weak donors and acceptors have been consistently defined at the energy level. A natural criterion of donor–acceptor agreement has been formulated by analyzing tabular data on the dissociation constants <i>K</i><sub>d</sub>(<i>T</i>) and <i>K</i><sub>a</sub>(<i>T</i>) in Ostwald’s dilution law for weak acids and alkalis (these constants are defined below). The fundamental role of the existence and possibilities of observing the compensation effect in binary electrolytes in determining the main energy parameters of phenomenological statistics of dilute weak hosts is emphasized.</p>","PeriodicalId":604,"journal":{"name":"JETP Letters","volume":"121 12","pages":"942 - 949"},"PeriodicalIF":1.3000,"publicationDate":"2025-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"JETP Letters","FirstCategoryId":"101","ListUrlMain":"https://link.springer.com/article/10.1134/S002136402560627X","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"PHYSICS, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

The properties of dilute, compensated “weak” electrolytes on the example of the binary mixture “acid + alkali + water” have been discussed within the framework of phenomenological energy statistics. The concepts of weak donors and acceptors have been consistently defined at the energy level. A natural criterion of donor–acceptor agreement has been formulated by analyzing tabular data on the dissociation constants Kd(T) and Ka(T) in Ostwald’s dilution law for weak acids and alkalis (these constants are defined below). The fundamental role of the existence and possibilities of observing the compensation effect in binary electrolytes in determining the main energy parameters of phenomenological statistics of dilute weak hosts is emphasized.

Abstract Image

二元酸性/碱性水溶液电解质
在现象学能量统计的框架内讨论了以“酸+碱+水”二元混合物为例的稀释补偿“弱”电解质的性质。弱供体和弱受体的概念一直是在能级上定义的。通过分析奥斯特瓦尔德弱酸和弱碱稀释定律中解离常数Kd(T)和Ka(T)的表格数据(这些常数的定义如下),制定了供体-受体一致性的自然标准。强调了二元电解质中补偿效应的存在和观测的可能性在确定稀弱主物质现象学统计的主要能量参数中的基本作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
JETP Letters
JETP Letters 物理-物理:综合
CiteScore
2.40
自引率
30.80%
发文量
164
审稿时长
3-6 weeks
期刊介绍: All topics of experimental and theoretical physics including gravitation, field theory, elementary particles and nuclei, plasma, nonlinear phenomena, condensed matter, superconductivity, superfluidity, lasers, and surfaces.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信