Electrochemical Performance of N-Doped Graphite @Carbon/ Red Phosphorous Composite for Lithium-Ion Secondary Batteries

IF 3.2 4区 工程技术 Q2 CHEMISTRY, MULTIDISCIPLINARY
Md Rasidul Islam Rocky, Venugopal Nulu, Keun Yong Sohn
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Abstract

Lithium-ion batteries (LIBs) are well-known for having three key features: lightweight, extended cycle life, and high energy density. This makes them perfect for various uses like electric cars and portable electronics. Red phosphorus (P) is low-cost, easily available, and possesses an excellent theoretical specific capacity (2596 mAh g−1) for use as the anode material in high-energy–density lithium-ion batteries (LIBs). However, P has poor conductivity (10–12 Sm−1), and colossal volume expansion during charging-discharging hinders its application in LIBs. Conversely, despite various reported anode materials, graphite remains the commercial choice for lithium-ion batteries. This study presents a nitrogen-doped graphite@carbon anode material composite with P that was designed and fabricated through a simple and scalable process. The nitrogen-doped graphite composite with carbon, NGC, effectively reduces harmful reactions between the electrolyte and graphite, ensuring stable electrode performance during charging and discharging. By incorporating optimized content of high-capacity phosphorus (P), NGC’s capacity and electronic conductivity improve, minimizing volume changes of raw red phosphorus through hybridization with the conductive carbon framework. The best optimized NGC/P2 composite shows a high initial discharge capacity of 1486 mAh g−1 and a reversible capacity of 530 mAh g−1 at a current density of 100 mA g−1 after 100 cycles, outperforming conventional graphite. This highlights innovative strategies for sustainable and efficient energy storage solutions.

Abstract Image

掺n石墨碳/红磷复合材料在锂离子二次电池中的电化学性能
众所周知,锂离子电池(lib)有三个关键特点:重量轻、循环寿命长、能量密度高。这使得它们非常适合各种用途,如电动汽车和便携式电子产品。红磷(P)成本低,易于获得,并且具有优异的理论比容量(2596 mAh g - 1),可作为高能量密度锂离子电池(LIBs)的负极材料。然而,P具有较差的电导率(10-12 Sm−1),并且在充放电过程中巨大的体积膨胀阻碍了其在锂离子电池中的应用。相反,尽管有各种各样的负极材料报道,石墨仍然是锂离子电池的商业选择。本研究提出了一种氮掺杂graphite@carbon与P复合的阳极材料,通过简单和可扩展的工艺设计和制造。氮掺杂石墨与碳(NGC)的复合材料有效地减少了电解质与石墨之间的有害反应,保证了电极在充放电过程中的稳定性能。通过加入高容量磷(P)的优化含量,NGC的容量和电子导电性得到提高,通过与导电碳骨架的杂交,使原料红磷的体积变化最小化。优化后的NGC/P2复合材料在100 mA g−1电流密度下,具有1486 mAh g−1的高初始放电容量和530 mAh g−1的可逆放电容量,优于传统石墨。这突出了可持续和高效储能解决方案的创新战略。
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来源期刊
Korean Journal of Chemical Engineering
Korean Journal of Chemical Engineering 工程技术-工程:化工
CiteScore
4.60
自引率
11.10%
发文量
310
审稿时长
4.7 months
期刊介绍: The Korean Journal of Chemical Engineering provides a global forum for the dissemination of research in chemical engineering. The Journal publishes significant research results obtained in the Asia-Pacific region, and simultaneously introduces recent technical progress made in other areas of the world to this region. Submitted research papers must be of potential industrial significance and specifically concerned with chemical engineering. The editors will give preference to papers having a clearly stated practical scope and applicability in the areas of chemical engineering, and to those where new theoretical concepts are supported by new experimental details. The Journal also regularly publishes featured reviews on emerging and industrially important subjects of chemical engineering as well as selected papers presented at international conferences on the subjects.
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