Sorption of Iron(III) Ions Using a Ti3C2Tx/Fe3O4 Heterostructured Magnetic Composite

IF 0.8 Q3 Engineering
N. R. Shilov, V. A. Ni, K. E. Magomedov, R. Z. Zeinalov, A. S. Omelyanchik, V. V. Rodionova
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引用次数: 0

Abstract

Two-dimensional MXene materials are attracting attention as nanoadsorbents for the removal of heavy metals from aqueous media. The adsorption properties of the magnetic composite Ti3C2Tx/Fe3O4 are investigated in relation to Fe(III) ions. It is found that the sorption capacity is 64.5 mg/g at a composite concentration of less than 10 mg/L. The kinetics of sorption is best described by a pseudo-second-order model, which indicates a chemical interaction between the sorbent and the sorbate. The calculated conditional activation energy (–17 kJ/mol) confirms that the sorption rate is limited by the diffusion stage. The magnetic characteristics of the composite provide the possibility of effective magnetic separation of the material after sorption.

Abstract Image

Ti3C2Tx/Fe3O4异质结构磁性复合材料对铁离子的吸附
二维MXene材料作为去除水中重金属的纳米吸附剂正受到人们的关注。研究了磁性复合材料Ti3C2Tx/Fe3O4对Fe(III)离子的吸附性能。在复合浓度小于10 mg/L时,吸附量为64.5 mg/g。吸附动力学最好用伪二阶模型来描述,该模型表明吸附剂和山梨酸盐之间存在化学相互作用。计算的条件活化能(-17 kJ/mol)证实了吸附速率受扩散阶段的限制。复合材料的磁性特性为吸附后的材料提供了有效磁分离的可能性。
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来源期刊
Nanotechnologies in Russia
Nanotechnologies in Russia NANOSCIENCE & NANOTECHNOLOGY-
CiteScore
1.20
自引率
0.00%
发文量
0
期刊介绍: Nanobiotechnology Reports publishes interdisciplinary research articles on fundamental aspects of the structure and properties of nanoscale objects and nanomaterials, polymeric and bioorganic molecules, and supramolecular and biohybrid complexes, as well as articles that discuss technologies for their preparation and processing, and practical implementation of products, devices, and nature-like systems based on them. The journal publishes original articles and reviews that meet the highest scientific quality standards in the following areas of science and technology studies: self-organizing structures and nanoassemblies; nanostructures, including nanotubes; functional and structural nanomaterials; polymeric, bioorganic, and hybrid nanomaterials; devices and products based on nanomaterials and nanotechnology; nanobiology and genetics, and omics technologies; nanobiomedicine and nanopharmaceutics; nanoelectronics and neuromorphic computing systems; neurocognitive systems and technologies; nanophotonics; natural science methods in a study of cultural heritage items; metrology, standardization, and monitoring in nanotechnology.
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