N. R. Shilov, V. A. Ni, K. E. Magomedov, R. Z. Zeinalov, A. S. Omelyanchik, V. V. Rodionova
{"title":"Sorption of Iron(III) Ions Using a Ti3C2Tx/Fe3O4 Heterostructured Magnetic Composite","authors":"N. R. Shilov, V. A. Ni, K. E. Magomedov, R. Z. Zeinalov, A. S. Omelyanchik, V. V. Rodionova","doi":"10.1134/S2635167625600312","DOIUrl":null,"url":null,"abstract":"<p>Two-dimensional MXene materials are attracting attention as nanoadsorbents for the removal of heavy metals from aqueous media. The adsorption properties of the magnetic composite Ti<sub>3</sub>C<sub>2</sub><i>T</i><sub><i>x</i></sub>/Fe<sub>3</sub>O<sub>4</sub> are investigated in relation to Fe(III) ions. It is found that the sorption capacity is 64.5 mg/g at a composite concentration of less than 10 mg/L. The kinetics of sorption is best described by a pseudo-second-order model, which indicates a chemical interaction between the sorbent and the sorbate. The calculated conditional activation energy (–17 kJ/mol) confirms that the sorption rate is limited by the diffusion stage. The magnetic characteristics of the composite provide the possibility of effective magnetic separation of the material after sorption.</p>","PeriodicalId":716,"journal":{"name":"Nanotechnologies in Russia","volume":"20 1","pages":"23 - 29"},"PeriodicalIF":0.8000,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanotechnologies in Russia","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S2635167625600312","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Engineering","Score":null,"Total":0}
引用次数: 0
Abstract
Two-dimensional MXene materials are attracting attention as nanoadsorbents for the removal of heavy metals from aqueous media. The adsorption properties of the magnetic composite Ti3C2Tx/Fe3O4 are investigated in relation to Fe(III) ions. It is found that the sorption capacity is 64.5 mg/g at a composite concentration of less than 10 mg/L. The kinetics of sorption is best described by a pseudo-second-order model, which indicates a chemical interaction between the sorbent and the sorbate. The calculated conditional activation energy (–17 kJ/mol) confirms that the sorption rate is limited by the diffusion stage. The magnetic characteristics of the composite provide the possibility of effective magnetic separation of the material after sorption.
期刊介绍:
Nanobiotechnology Reports publishes interdisciplinary research articles on fundamental aspects of the structure and properties of nanoscale objects and nanomaterials, polymeric and bioorganic molecules, and supramolecular and biohybrid complexes, as well as articles that discuss technologies for their preparation and processing, and practical implementation of products, devices, and nature-like systems based on them. The journal publishes original articles and reviews that meet the highest scientific quality standards in the following areas of science and technology studies: self-organizing structures and nanoassemblies; nanostructures, including nanotubes; functional and structural nanomaterials; polymeric, bioorganic, and hybrid nanomaterials; devices and products based on nanomaterials and nanotechnology; nanobiology and genetics, and omics technologies; nanobiomedicine and nanopharmaceutics; nanoelectronics and neuromorphic computing systems; neurocognitive systems and technologies; nanophotonics; natural science methods in a study of cultural heritage items; metrology, standardization, and monitoring in nanotechnology.