Xiaowu Jiang, Xiang Tan, Rongheng Xu, Enzhao Fang, Chi Yuan, Zihan Bai, Xiaoyan Gao, Lingni Ni
{"title":"Facile Fabrication of Polyhedral Oligomeric Silsesquioxane Block Bonded Cellulose Paper for Efficient Oil/Water Separation","authors":"Xiaowu Jiang, Xiang Tan, Rongheng Xu, Enzhao Fang, Chi Yuan, Zihan Bai, Xiaoyan Gao, Lingni Ni","doi":"10.1134/S1560090424601171","DOIUrl":null,"url":null,"abstract":"<p>We have successfully developed a superhydrophobic and superoleophilic cellulose paper by in situ formation of polyhedral oligomeric silsesquioxane (POSS) blocks on its surface. These POSS blocks endow the cellulose paper with an optimal micro-nano structure and hydrophobic composition, resulting in superhydrophobicity and enhanced abrasion resistance. The modified cellulose paper was characterized using scanning electron microscopy, energy dispersion spectroscopy, X-ray photoelectron spectroscopy, and X-ray diffraction analysis to confirm the structures. The oil-water separation performance of the as-prepared paper was validated through preferential adsorption and gravity-driven separation processes, demonstrating high separation efficiency and throughput for various oil/water mixtures. This innovative approach provides a promising solution for large-scale oil spill accidents while offering excellent reusability and stability.</p>","PeriodicalId":739,"journal":{"name":"Polymer Science, Series B","volume":"67 1","pages":""},"PeriodicalIF":1.0000,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series B","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S1560090424601171","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
We have successfully developed a superhydrophobic and superoleophilic cellulose paper by in situ formation of polyhedral oligomeric silsesquioxane (POSS) blocks on its surface. These POSS blocks endow the cellulose paper with an optimal micro-nano structure and hydrophobic composition, resulting in superhydrophobicity and enhanced abrasion resistance. The modified cellulose paper was characterized using scanning electron microscopy, energy dispersion spectroscopy, X-ray photoelectron spectroscopy, and X-ray diffraction analysis to confirm the structures. The oil-water separation performance of the as-prepared paper was validated through preferential adsorption and gravity-driven separation processes, demonstrating high separation efficiency and throughput for various oil/water mixtures. This innovative approach provides a promising solution for large-scale oil spill accidents while offering excellent reusability and stability.
期刊介绍:
Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed