Facile Fabrication of Polyhedral Oligomeric Silsesquioxane Block Bonded Cellulose Paper for Efficient Oil/Water Separation

IF 1 4区 化学 Q4 POLYMER SCIENCE
Xiaowu Jiang, Xiang Tan, Rongheng Xu, Enzhao Fang, Chi Yuan, Zihan Bai, Xiaoyan Gao, Lingni Ni
{"title":"Facile Fabrication of Polyhedral Oligomeric Silsesquioxane Block Bonded Cellulose Paper for Efficient Oil/Water Separation","authors":"Xiaowu Jiang,&nbsp;Xiang Tan,&nbsp;Rongheng Xu,&nbsp;Enzhao Fang,&nbsp;Chi Yuan,&nbsp;Zihan Bai,&nbsp;Xiaoyan Gao,&nbsp;Lingni Ni","doi":"10.1134/S1560090424601171","DOIUrl":null,"url":null,"abstract":"<p>We have successfully developed a superhydrophobic and superoleophilic cellulose paper by in situ formation of polyhedral oligomeric silsesquioxane (POSS) blocks on its surface. These POSS blocks endow the cellulose paper with an optimal micro-nano structure and hydrophobic composition, resulting in superhydrophobicity and enhanced abrasion resistance. The modified cellulose paper was characterized using scanning electron microscopy, energy dispersion spectroscopy, X-ray photoelectron spectroscopy, and X-ray diffraction analysis to confirm the structures. The oil-water separation performance of the as-prepared paper was validated through preferential adsorption and gravity-driven separation processes, demonstrating high separation efficiency and throughput for various oil/water mixtures. This innovative approach provides a promising solution for large-scale oil spill accidents while offering excellent reusability and stability.</p>","PeriodicalId":739,"journal":{"name":"Polymer Science, Series B","volume":"67 1","pages":""},"PeriodicalIF":1.0000,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series B","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S1560090424601171","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0

Abstract

We have successfully developed a superhydrophobic and superoleophilic cellulose paper by in situ formation of polyhedral oligomeric silsesquioxane (POSS) blocks on its surface. These POSS blocks endow the cellulose paper with an optimal micro-nano structure and hydrophobic composition, resulting in superhydrophobicity and enhanced abrasion resistance. The modified cellulose paper was characterized using scanning electron microscopy, energy dispersion spectroscopy, X-ray photoelectron spectroscopy, and X-ray diffraction analysis to confirm the structures. The oil-water separation performance of the as-prepared paper was validated through preferential adsorption and gravity-driven separation processes, demonstrating high separation efficiency and throughput for various oil/water mixtures. This innovative approach provides a promising solution for large-scale oil spill accidents while offering excellent reusability and stability.

Abstract Image

高效油水分离用多面体低聚硅氧烷嵌段粘合纤维素纸的简易制备
我们成功地在其表面原位形成多面体低聚硅氧烷(POSS)块,从而制备了一种超疏水和超亲油的纤维素纸。这些POSS块赋予纤维素纸最佳的微纳结构和疏水成分,从而产生超疏水性和增强的耐磨性。利用扫描电镜、能谱、x射线光电子能谱和x射线衍射分析对改性后的纤维素纸进行了结构表征。通过优先吸附和重力驱动分离实验,验证了制备纸的油水分离性能,对多种油水混合物具有较高的分离效率和吞吐量。这种创新的方法为大规模溢油事故提供了有前途的解决方案,同时具有出色的可重复使用性和稳定性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Polymer Science, Series B
Polymer Science, Series B 化学-高分子科学
CiteScore
1.80
自引率
8.30%
发文量
58
审稿时长
>0 weeks
期刊介绍: Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信