Characterization and Application of Cellulose-Humic Acid-Based Composite Superabsorbent Hydrogel

IF 1 4区 化学 Q4 POLYMER SCIENCE
Liu He, Yani Guo, Zhigang Wang, Kang Hou, Lijie Wei, Jiahui Zhang
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引用次数: 0

Abstract

Using acrylic acid, 2-acrylamido-2-methylpropanesulfonic acid, and N,N'-methylenebisacrylamide (MBA) along with leaf cellulose and weathered coal humic acid, a leaf cellulose-humic acid-based superabsorbent hydrogel was synthesized through a water-solution polymerization initiated by potassium persulfate. FTIR analysis confirmed the successful preparation of the composite hydrogel. SEM analysis showed the presence of numerous deep pores and pore structures on the surface of the composite superabsorbent hydrogel. TG analysis indicated that a good thermal stability of the composite hydrogel. The water absorption capacity, water retention ability, salt resistance, and water release performance of hydrogels were studied. Performance tests demonstrated that the water retention rate of superabsorbent hydrogel was 79.2% after 24 h at room temperature and 22.5% after 72 h. Sandy soil absorption release tests showed that the superabsorbent hydrogel could release water into sandy soil continuously, providing long-term water supply. In plant growth experiments, the incorporation of the superabsorbent hydrogel enhanced plant growth height, prolonged wilting time, and significantly promoted plant growth and development.

Abstract Image

纤维素-腐植酸基复合高吸水性凝胶的表征及应用
以丙烯酸、2-丙烯酰胺-2-甲基丙磺酸、N,N'-亚甲基双丙烯酰胺(MBA)、叶片纤维素和风化煤腐植酸为原料,通过过硫酸钾引发的水溶液聚合法制备了叶片纤维素-腐植酸基高吸水性水凝胶。FTIR分析证实了复合水凝胶的成功制备。SEM分析表明,复合高吸水性凝胶表面存在大量深孔隙和孔隙结构。热重分析表明该复合水凝胶具有良好的热稳定性。研究了水凝胶的吸水性、保水性、耐盐性和释水性能。性能试验表明,高吸水性水凝胶在室温下24 h保水率为79.2%,72 h保水率为22.5%。砂土吸收释放试验表明,高吸水性水凝胶可以连续向砂土中释放水分,提供长期供水。在植物生长实验中,高吸水性水凝胶的掺入提高了植物的生长高度,延长了植物的萎蔫时间,显著促进了植物的生长发育。
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来源期刊
Polymer Science, Series B
Polymer Science, Series B 化学-高分子科学
CiteScore
1.80
自引率
8.30%
发文量
58
审稿时长
>0 weeks
期刊介绍: Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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