Influence of the Configuration of Feedstock Injection Nozzles on the Hydrodynamic Regime and Performance of the Catalytic Cracking Riser-Reactor for Production of Light Olefins Using CFD Modeling

IF 0.6 4区 化学 Q4 CHEMISTRY, APPLIED
Saba Foroutan Ghazvini, E. N. Ivashkina, V. A. Chuzlov
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Abstract

The necessity of global market shift for production of light olefins influenced the catalytic cracking process in the direction of process optimization and construction modernization. This work investigated the influence of configuration (distribution) of feedstock injection nozzles on the hydrodynamic regime and performance of the riser-reactor for production of light gases (C1–C4). We considered eight feedstock injection nozzles in two cases. In case (a), eight nozzles are distributed in one plane around the riser-reactor, while in case (b), eight nozzles are distributed in two planes (four nozzles on each plane). Computational fluid dynamic modeling with four-lump reaction scheme with consideration of coke formation was used. Applied kinetic parameters were determined for an industrial riser-reactor with microspherical zeolite-containing catalyst. It was achieved that the distribution of solid-gas phases was enhanced for geometry (b). Mass fraction of light gases was obtained up to 0.5 (50 wt %). Moreover, the formation of coke was up to 14–15 and 9–10 wt % for geometry (a) and (b), respectively. It was observed that the main zone of chemical reactions is up to 10–15 m above the feedstock injection zone. Therefore, shortening the riser-reactor is recommended.

Abstract Image

基于CFD模型的进料喷嘴构型对轻烯烃催化裂化立管反应器水动力特性和性能的影响
全球轻烯烃生产市场转移的必要性,影响了催化裂化工艺向工艺优化和结构现代化的方向发展。本工作研究了原料喷射喷嘴的配置(分布)对生产轻气体(C1-C4)的立管反应器的流体动力状态和性能的影响。我们在两种情况下考虑了8个原料喷射喷嘴。在情形(a)中,8个喷嘴分布在立管-反应器周围的一个平面上;在情形(b)中,8个喷嘴分布在两个平面上(每个平面上有4个喷嘴)。采用考虑焦炭形成的四团反应模式计算流体动力学模型。以微球沸石为催化剂,确定了工业立管反应器的应用动力学参数。结果表明,固气相的分布在几何上得到了增强(b)。轻质气体的质量分数可达0.5 (50 wt %)。此外,焦炭的形成在几何形状(a)和(b)中分别高达14 - 15%和9-10 wt %。观察到化学反应的主要区域在原料注入区以上10-15 m处。因此,建议缩短立管-反应釜。
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来源期刊
CiteScore
1.60
自引率
11.10%
发文量
63
审稿时长
2-4 weeks
期刊介绍: Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
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