Photo-Fenton Reaction for the Decomposition of RR195 Dye in the Presence of the Metal-Organic Polymer MIL-53(Fe3+) and a Composite with Graphene Oxide

IF 0.5 4区 材料科学 Q4 CRYSTALLOGRAPHY
G. M. Kuz’micheva, A. A. Gainanova, N. K. Quang, E. V. Khramov, R. D. Svetogorov
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引用次数: 0

Abstract

The metal-organic polymer MIL-53(Fe) with the framework composition Fe(OH)(BDC)⋅(H2O)2 and the composite MIL-53(Fe)/GO (GO is graphene oxide) have been obtained by the solvothermal method and characterized by X-ray diffraction, X-ray absorption spectroscopy, IR Fourier spectroscopy, and scanning and transmission electron microscopy. It has been established that the MIL-53(Fe) in the MIL-53(Fe)/GO composition differs from the initial MIL-53(Fe) polymer by the absence of secondary phase (phases), a lower content of water molecules, a higher content of the solvent and Fe2+ ions, and the morphology and microstructure. In the photo-Fenton reaction, the degree of decomposition of RR195 dye in the presence of the MIL-53(Fe)/GO composite exceeds the degree of decomposition of the initial MIL-53(Fe) polymer, which remains almost invariable after three photo-reaction cycles.

Abstract Image

金属有机聚合物MIL-53(Fe3+)和氧化石墨烯复合材料存在下的光- fenton反应分解RR195染料
采用溶剂热法制备了骨架成分为Fe(OH)(BDC)⋅(H2O)2的金属有机聚合物MIL-53(Fe)和氧化石墨烯(GO为氧化石墨烯)复合材料MIL-53(Fe),并用x射线衍射、x射线吸收光谱、红外傅立叶光谱、扫描电镜和透射电镜对其进行了表征。结果表明,MIL-53(Fe)/GO组成中的MIL-53(Fe)与初始MIL-53(Fe)聚合物的不同之处在于缺少次级相(相),水分子含量较低,溶剂和Fe2+离子含量较高,形貌和微观结构也有所不同。在光- fenton反应中,在MIL-53(Fe)/GO复合物存在下,RR195染料的分解程度超过了初始MIL-53(Fe)聚合物的分解程度,在三个光反应循环后,MIL-53(Fe)聚合物几乎保持不变。
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来源期刊
Crystallography Reports
Crystallography Reports 化学-晶体学
CiteScore
1.10
自引率
28.60%
发文量
96
审稿时长
4-8 weeks
期刊介绍: Crystallography Reports is a journal that publishes original articles short communications, and reviews on various aspects of crystallography: diffraction and scattering of X-rays, electrons, and neutrons, determination of crystal structure of inorganic and organic substances, including proteins and other biological substances; UV-VIS and IR spectroscopy; growth, imperfect structure and physical properties of crystals; thin films, liquid crystals, nanomaterials, partially disordered systems, and the methods of studies.
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