Recycling of Iron Scrap Wastes into Cement Industry

IF 0.6 4区 化学 Q4 CHEMISTRY, APPLIED
N. M. Khalil, Yousif Algamal
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Abstract

This work aims at the exploitation of huge quantities of iron scrap wasted during iron production via recycling iron wastes using an electric arc furnace as a partial replacement to ordinary Portland cement to increase the production capacity of Portland cement without further firing and hence decreasing the ecological problems associated with its production. Six mixes were prepared with different additives of iron scrap wastes up to 50 wt. % on the expense of the cement content. Physico-mechanical properties namely water of consistency, setting time, hydration behavior, sintering parameters (bulk density and apparent porosity) as well as mechanical properties (cold crushing strength) were tested according to the International Standard Specifications. X-ray diffraction technique was used to investigate the phase compositions of the hydrated cement samples. The results indicated a marked improvement in the physicomechanical properties of the prepared cement mixes as the content of iron scrap waste additives increased. The mix composed of 70 wt. % Portland cement with 30 % iron scrap waste additive was considered as the optimum mix due to its outstanding physical and cementing properties (setting time; initial:48 min., final: 160 min., combined water; 43.25 %, bulk density; 3.22 g/cm3, apparent porosity; 10.46 %, cold crushing strength; 530 kg/cm2) which satisfy the requirement of International standard of mixed cement.

Abstract Image

废铁在水泥工业中的回收利用
本项目旨在利用电弧炉回收废铁,部分替代普通硅酸盐水泥,从而提高硅酸盐水泥的生产能力,从而减少生产过程中产生的生态问题,从而利用生产过程中产生的大量废铁。在水泥掺量为50%的前提下,用不同的废铁屑添加剂配制了6种混合料。物理力学性能,即水的稠度、凝结时间、水化行为、烧结参数(体积密度和表观孔隙率)以及力学性能(冷破碎强度)均按照国际标准规范进行测试。采用x射线衍射技术对水化水泥样品的物相组成进行了研究。结果表明,随着废铁添加剂含量的增加,所制水泥混合料的物理力学性能有明显改善。以70% wt. %的硅酸盐水泥和30%的废铁添加剂为混合料,其优异的物理性能和胶凝性能(初凝时间48 min,终凝时间160 min,结合水,容重43.25%,表观孔隙率3.22 g/cm3,冷抗强度10.46%,530 kg/cm2)满足国际混合水泥标准的要求,被认为是最佳混合料。
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来源期刊
CiteScore
1.60
自引率
11.10%
发文量
63
审稿时长
2-4 weeks
期刊介绍: Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
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