Revealing the Effect of Non-rubber Components of Natural Rubber on Its Radiation Resistance Performance

IF 4 2区 化学 Q2 POLYMER SCIENCE
En-Tao Luo, Liang Jing, Ling-Min Kong, Yu Peng, Hao Luo, Li-Juan Zhao, Zheng-Tian Xie, Jin-Rong Wu
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引用次数: 0

Abstract

Natural rubber (NR) is a crucial elastic material used for damping and sealing applications in the nuclear industry, but its mechanical stability under radiation remains inadequate. Current efforts to improve radiation resistance rely on the addition of antiradiation agents, however, the effects of the components and microstructures of NR itself on radiation resistance remain unclear. In this study, we compared the composition and structure differences of four typical commercially used NR materials and investigated their effects on gamma radiation resistance. Furthermore, we examined the impact of non-rubber components (NRC) in NR on radiation resistance using deproteinized and dephosphorylated NR model samples. Our results revealed that NRC, such as proteins and phospholipids can enhance the strength of natural rubber before radiation exposure. However, after the removal of NRC, the samples exhibited improved mechanical stability under irradiation. Additionally, the ash content in NR could also influence the radiation resistance, as metal ions may react with the active centers produced by radiation, thereby enhancing the radiation resistance of the rubber. This work identifies the effect of non-rubber components in NR on radiation resistance and may serve as a reference for screening and developing radiation-resistant NR materials.

揭示天然橡胶非橡胶组分对其耐辐射性能的影响
天然橡胶(NR)是核工业中用于阻尼和密封的重要弹性材料,但其在辐射下的机械稳定性仍然不足。目前提高抗辐射能力的努力主要依靠抗辐射剂的加入,然而NR本身的成分和微观结构对抗辐射能力的影响尚不清楚。在本研究中,我们比较了四种典型的商用NR材料的组成和结构差异,并研究了它们对抗伽马辐射的影响。此外,我们利用去蛋白化和去磷酸化的NR模型样品,研究了NR中非橡胶组分(NRC)对辐射抗性的影响。我们的研究结果表明,NRC,如蛋白质和磷脂可以增强天然橡胶在辐射暴露前的强度。然而,去除NRC后,样品在辐照下表现出更好的机械稳定性。此外,NR中的灰分含量也会影响橡胶的耐辐射性,因为金属离子可能会与辐射产生的活性中心发生反应,从而增强橡胶的耐辐射性。本工作确定了NR中非橡胶组分对耐辐射性能的影响,可为耐辐射NR材料的筛选和开发提供参考。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Chinese Journal of Polymer Science
Chinese Journal of Polymer Science 化学-高分子科学
CiteScore
7.10
自引率
11.60%
发文量
218
审稿时长
6.0 months
期刊介绍: Chinese Journal of Polymer Science (CJPS) is a monthly journal published in English and sponsored by the Chinese Chemical Society and the Institute of Chemistry, Chinese Academy of Sciences. CJPS is edited by a distinguished Editorial Board headed by Professor Qi-Feng Zhou and supported by an International Advisory Board in which many famous active polymer scientists all over the world are included. The journal was first published in 1983 under the title Polymer Communications and has the current name since 1985. CJPS is a peer-reviewed journal dedicated to the timely publication of original research ideas and results in the field of polymer science. The issues may carry regular papers, rapid communications and notes as well as feature articles. As a leading polymer journal in China published in English, CJPS reflects the new achievements obtained in various laboratories of China, CJPS also includes papers submitted by scientists of different countries and regions outside of China, reflecting the international nature of the journal.
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