The role of graphite, graphene nanoplatelets, and MXene in improving the physical properties and workability of bitumen

IF 3.9 3区 工程技术 Q2 CONSTRUCTION & BUILDING TECHNOLOGY
Amirhosein Dashtbozorg, Behnaz Safarianbana, Mehdi Shanbedi, Ahmad Amiri
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Abstract

This study explores the enhancement of thermal and rheological properties of 60/70 grade bitumen by the incorporation of nano-additives, including graphite, graphene nanoplatelets (GNP), and MXene. This research presents the first performance evaluation of MXene as a nano-additive in bitumen, comparing its effects directly with those of other common additives, GNP and graphite, under identical conditions. Bitumen was modified to assess the impact of these nano-additives on properties such as softening point, penetration, flash point, dynamic shear, and viscosity. Using high-shear mixing and curing methods, modified bitumen samples were prepared and tested following ASTM standards to analyze their workability and performance at elevated temperatures. Key findings show that MXene significantly enhances the softening point (a 1.51 °C increase) and dynamic shear modulus, offering superior high-temperature stability compared to GNP and graphite. Additionally, GNP-modified bitumen exhibited the most substantial reduction in weight loss during aging tests (74% decrease), suggesting improved oxidative stability. Optimal performance across parameters was observed at 1–2% concentrations of nano-additives, with higher dosages resulting in agglomeration and reduced effectiveness. These findings highlight MXene’s potential as an innovative additive for improving bitumen’s durability, with a 59.2% enhancement in rutting resistance at 1–2% concentration, and recommend field trials to validate long-term performance in practical applications. Field validation studies are recommended to assess long-term durability under traffic loading.

Graphical abstract

石墨、石墨烯纳米片和MXene在改善沥青物理性能和和易性方面的作用
本研究探讨了通过加入纳米添加剂(包括石墨、石墨烯纳米片(GNP)和MXene)来增强60/70级沥青的热性能和流变性能。本研究首次对MXene作为沥青纳米添加剂进行了性能评价,并将其与其他常用添加剂GNP和石墨在相同条件下的效果进行了直接比较。对沥青进行改性,以评估这些纳米添加剂对软化点、渗透、闪点、动态剪切和粘度等性能的影响。采用高剪切混合和固化方法,制备了改性沥青样品,并按照ASTM标准进行了测试,以分析其在高温下的可加工性和性能。主要研究结果表明,与GNP和石墨相比,MXene显著提高了软化点(提高了1.51℃)和动剪切模量,具有优越的高温稳定性。此外,gnp改性沥青在老化试验中表现出最显著的减重效果(减少74%),表明氧化稳定性得到改善。在1-2%的纳米添加剂浓度下,各参数的性能最佳,但剂量越大,效果越差。这些发现突出了MXene作为提高沥青耐久性的创新添加剂的潜力,在1-2%的浓度下,MXene的车辙阻力提高了59.2%,并建议进行现场试验,以验证其在实际应用中的长期性能。建议进行实地验证研究,以评估交通载荷下的长期耐久性。图形抽象
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来源期刊
Materials and Structures
Materials and Structures 工程技术-材料科学:综合
CiteScore
6.40
自引率
7.90%
发文量
222
审稿时长
5.9 months
期刊介绍: Materials and Structures, the flagship publication of the International Union of Laboratories and Experts in Construction Materials, Systems and Structures (RILEM), provides a unique international and interdisciplinary forum for new research findings on the performance of construction materials. A leader in cutting-edge research, the journal is dedicated to the publication of high quality papers examining the fundamental properties of building materials, their characterization and processing techniques, modeling, standardization of test methods, and the application of research results in building and civil engineering. Materials and Structures also publishes comprehensive reports prepared by the RILEM’s technical committees.
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