High-Temperature Oxidation Behavior of GH5188 Superalloy Foil and Its Effect on Tensile Performance

IF 1.5 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING
Han Li, Yong Yang, Wei Tian, Yan-fei Liu, Hong-jian Zhao, Yong-gang Wang, Hai-shan Li, Yu-xuan Shao, Sheng-yong Gao, Ai-min Li, Huan-huan Zhang, Dong-yang Li
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Abstract

In this study, the oxidation behavior of a 0.3 mm thick GH5188 alloy foil in air at 800–1150 ℃ and its effect on tensile properties were investigated. The results showed that the oxidation kinetics of the GH5188 alloy foil followed a parabolic law and exhibited a characteristic a two-stage oxidation process. A protective oxide scale primarily composed of Cr2O3 and MnCr2O4 formed on the foil surface. The consumption of chromium led to the formation and deepening of a carbide-free precipitation zone within the foil. However, thermal stress and growth stress led to stress concentration within the Cr2O3 layer, resulting in spallation of the oxide scale. After oxidation, strip-like precipitates interconnected at grain boundaries, forming a network structure, while fine granular precipitates were diffusely distributed within the grains. The room temperature tensile strength and plasticity of the alloy foil decreased significantly. The tensile strength and elongation of the initial state alloy foil are 1045.7 MPa and 66.4%, respectively. After oxidation at 1150 °C for 50 h, the tensile strength and elongation of the specimen decrease to 888.7 MPa and 35.6%. The fracture exhibited brittle fracture features due to the network structure within the matrix. Additionally, the tensile properties at high temperatures further deteriorated. After oxidation at 1150 °C for 50 h, the high-temperature tensile strength and elongation of the specimen decrease to 516.2 MPa and 30.4%. The deterioration of high-temperature tensile properties was related to stress concentration at oxidation-induced voids.

GH5188高温合金箔的高温氧化行为及其对拉伸性能的影响
研究了0.3 mm厚GH5188合金箔在800 ~ 1150℃空气中的氧化行为及其对拉伸性能的影响。结果表明:GH5188合金箔的氧化动力学遵循抛物线规律,呈现出两阶段氧化的特征;在箔表面形成了以Cr2O3和MnCr2O4为主的保护性氧化层。铬的消耗导致箔内无碳化物析出区形成和加深。而热应力和生长应力导致Cr2O3层内应力集中,导致氧化皮剥落。氧化后,条状析出相在晶界处相互连接,形成网状结构,细粒状析出相在晶粒内弥散分布。合金箔的室温拉伸强度和塑性明显下降。初始态合金箔的抗拉强度和伸长率分别为1045.7 MPa和66.4%。在1150℃氧化50 h后,试样的抗拉强度和伸长率分别降至888.7 MPa和35.6%。由于基体内部呈网状结构,断口呈现脆性断裂特征。此外,高温拉伸性能进一步恶化。在1150℃氧化50 h后,试样的高温抗拉强度和伸长率分别降至516.2 MPa和30.4%。高温拉伸性能的恶化与氧化诱导空洞处的应力集中有关。
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来源期刊
Oxidation of Metals
Oxidation of Metals 工程技术-冶金工程
CiteScore
5.10
自引率
9.10%
发文量
47
审稿时长
2.2 months
期刊介绍: Oxidation of Metals is the premier source for the rapid dissemination of current research on all aspects of the science of gas-solid reactions at temperatures greater than about 400˚C, with primary focus on the high-temperature corrosion of bulk and coated systems. This authoritative bi-monthly publishes original scientific papers on kinetics, mechanisms, studies of scales from structural and morphological viewpoints, transport properties in scales, phase-boundary reactions, and much more. Articles may discuss both theoretical and experimental work related to gas-solid reactions at the surface or near-surface of a material exposed to elevated temperatures, including reactions with oxygen, nitrogen, sulfur, carbon and halogens. In addition, Oxidation of Metals publishes the results of frontier research concerned with deposit-induced attack. Review papers and short technical notes are encouraged.
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