{"title":"Electron cloud engineering enables low-potential multi-redox-center organic anodes: towards dendrite-free, high-energy aqueous zinc-ion batteries","authors":"Haitao Zou, Shushun Liu, Anning Jiang, Yong Chen, Fuxu Zhan, Lili Liu, Jinlei Tian, Jijun Feng","doi":"10.1007/s11581-025-06477-w","DOIUrl":null,"url":null,"abstract":"<div><p>Developing organic anode materials to fabricate zinc metal-free zinc ion batteries (ZF-ZIBs) is a prospective strategy to address the safety risks aroused by zinc dendrite. However, previously reported organic anodes are often criticized for their high potentials or low capacities. Here, an enlarged redox-active π-conjugated molecule, diquinoxalino[2,3-f:2′,3′-h]quinoxalino-[2,3-i]phenazine-2,3,8,9,17,18,23,24-octam-ethoxy-13,28-dione (DQPOD), is developed based on the electron cloud regulation strategy. Notably, the incorporation of the eight methoxy groups effectively increases the electron cloud density of the conjugated system, thus enabling the material to obtain an eminently low average discharge potential (0.44 V vs. Zn/Zn<sup>2+</sup>), while the enlarged π-conjugated redox-active structure produces an exceptional theoretical capacity of 390.5 mAh g<sup>−1</sup> and distinguished electrochemical performance. As expected, DQPOD exhibits superior practical capacity (300.22 mAh g<sup>−1</sup> at 0.1 A g<sup>−1</sup>), satisfying cyclic stability and excellent rate capability. The MnO<sub>2</sub>/DQPOD full battery presents an average operating voltage of up to 0.81 V at 5 A g<sup>−1</sup> and an ultrahigh power density of 3636 W kg<sup>−1</sup>. The novel molecular architecture engineering strategy of DQPOD not only furnishes a unique outlook about the design of organic anode materials but also contributes valuable insights to the ongoing discourse of high-safety, high-energy–density metal-ion battery systems.</p><h3>Graphical Abstract</h3><p>Low-potential multi-electron redox organic anodes for zinc ion batteries are developed through active centers combination and electron cloud regulation strategy.</p>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":599,"journal":{"name":"Ionics","volume":"31 8","pages":"8085 - 8096"},"PeriodicalIF":2.6000,"publicationDate":"2025-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ionics","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11581-025-06477-w","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Developing organic anode materials to fabricate zinc metal-free zinc ion batteries (ZF-ZIBs) is a prospective strategy to address the safety risks aroused by zinc dendrite. However, previously reported organic anodes are often criticized for their high potentials or low capacities. Here, an enlarged redox-active π-conjugated molecule, diquinoxalino[2,3-f:2′,3′-h]quinoxalino-[2,3-i]phenazine-2,3,8,9,17,18,23,24-octam-ethoxy-13,28-dione (DQPOD), is developed based on the electron cloud regulation strategy. Notably, the incorporation of the eight methoxy groups effectively increases the electron cloud density of the conjugated system, thus enabling the material to obtain an eminently low average discharge potential (0.44 V vs. Zn/Zn2+), while the enlarged π-conjugated redox-active structure produces an exceptional theoretical capacity of 390.5 mAh g−1 and distinguished electrochemical performance. As expected, DQPOD exhibits superior practical capacity (300.22 mAh g−1 at 0.1 A g−1), satisfying cyclic stability and excellent rate capability. The MnO2/DQPOD full battery presents an average operating voltage of up to 0.81 V at 5 A g−1 and an ultrahigh power density of 3636 W kg−1. The novel molecular architecture engineering strategy of DQPOD not only furnishes a unique outlook about the design of organic anode materials but also contributes valuable insights to the ongoing discourse of high-safety, high-energy–density metal-ion battery systems.
Graphical Abstract
Low-potential multi-electron redox organic anodes for zinc ion batteries are developed through active centers combination and electron cloud regulation strategy.
开发有机负极材料制备无锌金属锌离子电池是解决锌枝晶安全隐患的前瞻性策略。然而,以前报道的有机阳极往往被批评为高电位或低容量。本文基于电子云调控策略,构建了一种具有氧化还原活性的扩大π共轭分子——二喹草利诺[2,3-f:2′,3′-h]喹草利诺-[2,3-i]非那嗪-2,3,8,9,17,18,23,24-八辛-乙氧基-13,28-二酮(DQPOD)。值得注意的是,8个甲氧基的加入有效地增加了共轭体系的电子云密度,从而使材料获得了极低的平均放电电位(0.44 V vs. Zn/Zn2+),而扩大的π共轭氧化还原活性结构产生了优异的理论容量390.5 mAh g−1和卓越的电化学性能。正如预期的那样,DQPOD具有优异的实用容量(在0.1 A g−1时为300.22 mAh g−1),满足循环稳定性和出色的倍率能力。MnO2/DQPOD全电池在5 A g−1时的平均工作电压高达0.81 V,功率密度高达3636w kg−1。DQPOD的新型分子结构工程策略不仅为有机负极材料的设计提供了独特的前景,而且为高安全、高能量密度金属离子电池系统的发展提供了宝贵的见解。摘要通过活性中心组合和电子云调控策略,研制了锌离子电池用低电位多电子氧化还原有机阳极。
期刊介绍:
Ionics is publishing original results in the fields of science and technology of ionic motion. This includes theoretical, experimental and practical work on electrolytes, electrode, ionic/electronic interfaces, ionic transport aspects of corrosion, galvanic cells, e.g. for thermodynamic and kinetic studies, batteries, fuel cells, sensors and electrochromics. Fast solid ionic conductors are presently providing new opportunities in view of several advantages, in addition to conventional liquid electrolytes.