N-Isopropyl-N′,N′-diorganyl-N-(silylmethyl)ureas: synthesis, structure, and biological activity

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2025-07-10 DOI:10.1007/s11172-024-4672-1

N. F. Lazareva, N. V. Filinova, M. A. Alekseev, M. S. Molokeev

引用次数: 0

Abstract

The method for the synthesis of N-isopropyl-N′,N′-diorganyl-N-[(triethoxysilyl)-methyl]ureas was optimized. The reaction of these compounds with triethanolamine afforded the corresponding N-(silatranylmethyl)ureas R₂NC(O)N(Prⁱ)CH₂Si(OCH₂CH₂)₃N (R = Me, Ph). The structures of the new compounds were confirmed by multinuclear NMR spectroscopy. The structure of the silane Ph₂NC(O)N(Prⁱ)CH₂Si(OEt)₃ was established by X-ray diffraction. Preliminary data on the effect of N-isopropyl-N′,N′-dimethyl-N-(silatranylmethyl)urea on the parameters of the rapeseed and wheat growth were obtained.

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N-异丙基-N′，N′-二有机基-N-（硅基甲基）脲的合成、结构和生物活性

优化了N-异丙基-N′，N′-二有机基-N-[（三乙氧基）甲基]脲的合成方法。这些化合物与三乙醇胺反应得到相应的N-（硅烷基甲基）脲R2NC(O)N(Pri)CH2Si(OCH2CH2)3N （R = Me, Ph）。新化合物的结构经多核磁共振波谱证实。通过x射线衍射确定了硅烷Ph2NC(O)N(Pri)CH2Si(OEt)3的结构。初步研究了N-异丙基N′、N′-二甲基N-（硅丙基甲基）尿素对油菜籽和小麦生长参数的影响。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.