Immobilization of Boron-Containing Radioactive Waste from Nuclear Power Plants in Magnesium Potassium Phosphate Compound

IF 1 Q4 CHEMISTRY, INORGANIC & NUCLEAR
S. A. Fimina, N. D. Chalysheva, K. Yu. Belova, S. E. Vinokurov
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Abstract

Samples of magnesium potassium phosphate compound containing boron-containing evaporator bottom simulant after concentrating liquid radioactive waste from nuclear power plants were synthesized. The possibility of solidifying up to 14 wt % evaporator bottom simulant components into a compound containing 15–20 wt % wollastonite was demonstrated. The phase composition of the samples obtained, their compressive strength, resistance to thermal cycles, water resistance, and hydrolytic durability were determined. The integral 137Cs leaching rate is 5.7 × 10−4 g/(cm2 day), and the leaching index is 10.7. The quality indicators of the compound obtained meet the regulatory requirements for a compound for solidifying radioactive waste.

Abstract Image

核电厂含硼放射性废物在磷酸镁钾化合物中的固定化研究
合成了核电站放射性废液浓缩后的含硼磷酸盐镁钾化合物蒸发器底模拟物样品。证明了将高达14wt %的蒸发器底部模拟组分固化成含有15 - 20wt %硅灰石的化合物的可能性。测定了所得样品的相组成、抗压强度、耐热性、耐水性和水解耐久性。137Cs的整体浸出速率为5.7 × 10−4 g/(cm2 day),浸出指数为10.7。所得化合物的各项质量指标均符合放射性废物固化用化合物的法规要求。
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来源期刊
Radiochemistry
Radiochemistry CHEMISTRY, INORGANIC & NUCLEAR-
CiteScore
1.30
自引率
33.30%
发文量
51
期刊介绍: Radiochemistry  is a journal that covers the theoretical and applied aspects of radiochemistry, including basic nuclear physical properties of radionuclides; chemistry of radioactive elements and their compounds; the occurrence and behavior of natural and artificial radionuclides in the environment; nuclear fuel cycle; radiochemical analysis methods and devices; production and isolation of radionuclides, synthesis of labeled compounds, new applications of radioactive tracers; radiochemical aspects of nuclear medicine; radiation chemistry and after-effects of nuclear transformations.
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