Effect of Filler Content on Realizing Self-Lubricating and Ultra-Low Wear of PTFE Composites: A Mechanism Study

IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL
Shu Yang, Zhenyu Liu, Yingxi Xie, Longsheng Lu, Guodian Huang, Wanshun Wang
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Abstract

Polytetrafluoroethylene (PTFE) improves friction and wear performance by forming a transfer film on counterfaces. However, its high wear rates reduce the fitting accuracy and limit its service life. Adding fillers to PTFE can significantly lower its wear rate. Early theory suggests that fillers reduce wear by providing preferential load support and preventing the development and propagation of subsurface cracks. However, this theory cannot explain the ultra-low wear behavior of some nano fillers and lamellar fillers, and it is also found that the model ignored the effect of the transfer film. With the in-depth study of the wear reduction mechanism, it has been revealed that the ultra-low wear behavior of these fillers is closely related to tribochemistry and the formation of the transfer film. Moreover, research has shown that the type of filler affects the tribological properties of composites. Therefore, it is essential to investigate the wear-reduction mechanisms of different fillers. In this study, we investigated the wear reduction mechanisms of four representative filler-filled PTFE composites, which included carbon-based materials, metals, polar polymers, and non-polar polymers. The results show that (1) the accumulation and preferential load support of fillers on the polymer surface determine its wear resistance, and (2) filler-induced PTFE chain breakage promotes tribochemistry and facilitates the formation of adherent transfer films. Based on these findings, recommendations are provided for the design of low-wear PTFE friction systems.

Graphical Abstract

Abstract Image

填料含量对PTFE复合材料自润滑和超低磨损影响的机理研究
聚四氟乙烯(PTFE)通过在表面形成转移膜来改善摩擦和磨损性能。然而,其高磨损率降低了配合精度,限制了其使用寿命。在PTFE中加入填料可以显著降低其磨损率。早期的理论认为,填料通过提供优先负载支持和防止地下裂纹的发展和扩展来减少磨损。然而,该理论不能解释某些纳米填料和片层填料的超低磨损行为,并且还发现该模型忽略了转移膜的影响。随着对其减磨机理的深入研究,揭示了这些填料的超低磨损行为与摩擦化学和转移膜的形成密切相关。此外,研究表明,填料的类型影响复合材料的摩擦学性能。因此,有必要研究不同填料的减磨机理。本文研究了碳基材料、金属、极性聚合物和非极性聚合物四种具有代表性的填料填充PTFE复合材料的减磨机理。结果表明:(1)填料在聚合物表面的积累和优先负载支撑决定了聚合物的耐磨性;(2)填料引起的PTFE链断裂促进了摩擦化学反应,有利于粘附转移膜的形成。基于这些发现,提出了设计低磨损PTFE摩擦系统的建议。图形抽象
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来源期刊
Tribology Letters
Tribology Letters 工程技术-工程:化工
CiteScore
5.30
自引率
9.40%
发文量
116
审稿时长
2.5 months
期刊介绍: Tribology Letters is devoted to the development of the science of tribology and its applications, particularly focusing on publishing high-quality papers at the forefront of tribological science and that address the fundamentals of friction, lubrication, wear, or adhesion. The journal facilitates communication and exchange of seminal ideas among thousands of practitioners who are engaged worldwide in the pursuit of tribology-based science and technology.
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