Multilevel dispersion induced graphdiyne mixed-matrix membranes for ethanol recovery

IF 4.5 3区 工程技术 Q2 ENGINEERING, CHEMICAL
Sen Li, Xiaoting Zhou, Tieyan Li, Yingzhou Lu, Chunxi Li, Hongwei Fan, Hong Meng
{"title":"Multilevel dispersion induced graphdiyne mixed-matrix membranes for ethanol recovery","authors":"Sen Li,&nbsp;Xiaoting Zhou,&nbsp;Tieyan Li,&nbsp;Yingzhou Lu,&nbsp;Chunxi Li,&nbsp;Hongwei Fan,&nbsp;Hong Meng","doi":"10.1007/s11705-025-2581-y","DOIUrl":null,"url":null,"abstract":"<div><p>Graphdiyne represents an emerging nanofiller of mixed matrix membranes for high-performance alcohol recovery by pervaporation due to its unique alkyne-rich and porous framework and hydrophobicity. However, such membranes often encounter a persistent challenge of nanofiller agglomeration within the polymer matrix, which diminishes the efficacy of graphdiyne during alcohol recovery. This study proposes a multilevel dispersion strategy that synergistically combines <i>in situ</i> confined growth, ultrasonication, atomization, and rotational shearing throughout membrane preparation to mitigate particle aggregation. The particle agglomeration scale in the polydimethylsiloxane matrix can be effectively reduced from 660 nm of triphenylamine-based graphdiyne to about 291 nm compared to the general stirring-casting method. The mixed matrix membrane loaded with 2.5 wt % triphenylamine-based graphdiyne demonstrated a permeate flux of 2.35 kg·m<sup>−2</sup>·h<sup>−1</sup> alongside a separation factor of 11.31 for a 5 wt % ethanol/water solution. Compared to the stirring-casting method, these performances represent enhancements of 41% in permeate flux and 80% in separation factor. Furthermore, a 96 h-continuous pervaporation test indicated the robust stability of the membrane, underscoring the potential for industrial alcohol recovery.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"19 12","pages":""},"PeriodicalIF":4.5000,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Frontiers of Chemical Science and Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11705-025-2581-y","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0

Abstract

Graphdiyne represents an emerging nanofiller of mixed matrix membranes for high-performance alcohol recovery by pervaporation due to its unique alkyne-rich and porous framework and hydrophobicity. However, such membranes often encounter a persistent challenge of nanofiller agglomeration within the polymer matrix, which diminishes the efficacy of graphdiyne during alcohol recovery. This study proposes a multilevel dispersion strategy that synergistically combines in situ confined growth, ultrasonication, atomization, and rotational shearing throughout membrane preparation to mitigate particle aggregation. The particle agglomeration scale in the polydimethylsiloxane matrix can be effectively reduced from 660 nm of triphenylamine-based graphdiyne to about 291 nm compared to the general stirring-casting method. The mixed matrix membrane loaded with 2.5 wt % triphenylamine-based graphdiyne demonstrated a permeate flux of 2.35 kg·m−2·h−1 alongside a separation factor of 11.31 for a 5 wt % ethanol/water solution. Compared to the stirring-casting method, these performances represent enhancements of 41% in permeate flux and 80% in separation factor. Furthermore, a 96 h-continuous pervaporation test indicated the robust stability of the membrane, underscoring the potential for industrial alcohol recovery.

多层分散诱导石墨炔混合基质膜用于乙醇回收
石墨炔由于其独特的富炔多孔结构和疏水性,代表了一种新兴的混合基质膜纳米填料,用于通过渗透蒸发实现高性能醇回收。然而,这种膜经常遇到纳米填料在聚合物基体内聚集的持续挑战,这降低了乙醇回收过程中石墨炔的功效。本研究提出了一种多层分散策略,在整个膜制备过程中协同结合原位受限生长、超声、雾化和旋转剪切来减轻颗粒聚集。与一般的搅拌浇铸法相比,聚二甲基硅氧烷基体中的颗粒团聚尺度可以有效地从三苯胺基石墨炔的660 nm减小到291 nm左右。在5 wt %乙醇/水溶液中,负载2.5 wt %三苯胺基石墨炔的混合基质膜的渗透通量为2.35 kg·m−2·h−1,分离系数为11.31。与搅拌铸造法相比,这些性能使渗透通量提高了41%,分离系数提高了80%。此外,96 h连续渗透蒸发试验表明,该膜具有强大的稳定性,强调了工业酒精回收的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
CiteScore
7.60
自引率
6.70%
发文量
868
审稿时长
1 months
期刊介绍: Frontiers of Chemical Science and Engineering presents the latest developments in chemical science and engineering, emphasizing emerging and multidisciplinary fields and international trends in research and development. The journal promotes communication and exchange between scientists all over the world. The contents include original reviews, research papers and short communications. Coverage includes catalysis and reaction engineering, clean energy, functional material, nanotechnology and nanoscience, biomaterials and biotechnology, particle technology and multiphase processing, separation science and technology, sustainable technologies and green processing.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信