Multifunctional PANI-LDH nanocomposites: from efficient cango red mineralization to high-yield solar hydrogen generation

IF 6 2区 工程技术 Q2 ENERGY & FUELS
Pritam Hait , Rajeev Mehta , Soumen Basu
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引用次数: 0

Abstract

In this study, a binary nanocomposite comprising polyaniline (PANI) and nickel–aluminum layered double hydroxide (Ni–Al LDH) was synthesized via an oxidative polymerization method, with varying LDH loadings (2, 5, and 7 wt%). Comprehensive physicochemical characterization—including UV–Vis DRS, photoluminescence (PL), XRD, XPS, BET, and EDS—was employed to investigate the optical, structural, compositional, and textural attributes of the materials. From FESEM the porous morphology of PANI and the hierarchical, flower-like morphology of LDH were observed. The photocatalytic performance of the composite was evaluated for Congo red (CR) dye degradation and photocatalytic hydrogen evolution under visible light irradiation. After 120 min, the system achieved 98 % dye removal and approximately 50 % mineralization, as confirmed by total organic carbon analysis. Kinetic studies indicated pseudo-first-order behaviour, with the rate constant exceeding those of pristine PANI, LDH, and TiO2-P25 by factors of 6, 8, and 9, respectively, evidencing a pronounced synergistic interaction. Operational parameters such as pH, catalyst loading, illumination area, and the presence of scavengers significantly influenced activity. The composite maintained ∼ 70 % catalytic efficiency over six consecutive cycles. HRMS enabled identification of intermediate and final degradation products. Under methanol-assisted conditions, the composite exhibited a hydrogen evolution AQE of 20 %, with AQEs of 18 %, 21 %, and 16 % in acidic, basic, and neutral media, respectively. These results underscore the composite’s bifunctionality for environmental remediation and solar-driven energy conversion.
多功能聚苯乙烯- ldh纳米复合材料:从高效高锰矿化到高产能太阳能制氢
在这项研究中,通过氧化聚合方法合成了由聚苯胺(PANI)和镍铝层状双氢氧化物(Ni-Al LDH)组成的二元纳米复合材料,LDH的负载不同(2、5和7 wt%)。采用紫外-可见DRS、光致发光(PL)、XRD、XPS、BET和eds等综合理化表征手段对材料的光学、结构、组成和织构属性进行了表征。从FESEM上观察到聚苯胺的多孔形态和LDH的层次化花状形态。考察了该复合材料在可见光照射下对刚果红(CR)染料的降解和光催化析氢性能。经总有机碳分析证实,在120分钟后,该体系实现了98%的染料去除率和大约50%的矿化。动力学研究显示出伪一级行为,其速率常数分别超过原始PANI, LDH和TiO2-P25的6倍,8倍和9倍,证明了明显的协同作用。操作参数,如pH值、催化剂负载、光照面积和清除剂的存在显著影响活性。该复合材料在连续六个循环中保持了约70%的催化效率。HRMS能够识别中间和最终降解产物。在甲醇辅助条件下,复合材料的析氢率为20%,在酸性、碱性和中性介质中分别为18%、21%和16%。这些结果强调了复合材料在环境修复和太阳能驱动的能量转换方面的双重功能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Solar Energy
Solar Energy 工程技术-能源与燃料
CiteScore
13.90
自引率
9.00%
发文量
0
审稿时长
47 days
期刊介绍: Solar Energy welcomes manuscripts presenting information not previously published in journals on any aspect of solar energy research, development, application, measurement or policy. The term "solar energy" in this context includes the indirect uses such as wind energy and biomass
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