{"title":"Tuning growth parameter for the controlled synthesis of 2D WS2","authors":"Nishtha Sagta, Ajay Kumar Mishra","doi":"10.1016/j.cap.2025.09.018","DOIUrl":null,"url":null,"abstract":"<div><div>The atmospheric pressure chemical vapor deposition (APCVD) synthesis of high-quality 2D WS<sub>2</sub> (tungsten disulfide) critically depends on the precise timing of sulfur vapor introduction. This study investigates the role of sulfur-rich environment and growth time on the surface morphology of 2D WS<sub>2</sub> films on the silicon substrate. Three different varying sets of parameters, designated as SP<sub>1</sub>, SP<sub>2</sub>, and SP<sub>3</sub>, were examined to optimize the time of sulfur vapor introduction. This process enabled the formation of large mono- and bi-layer triangular islands, with flake sizes ranging from ∼70 to 164 μm, as well as long few-layer structures. The atomically thin WS<sub>2</sub> exhibited strong photoluminescence (PL) at ∼1.93 eV, with a ∼70-fold enhancement and a full-width at half maximum (FWHM) of ∼12 nm. The optimized SP<sub>3</sub> parameters were applied using the sapphire substrate, and the results were consistent. Thus, this study highlights the crucial role of sulfur vapor synchronization in WS<sub>2</sub> synthesis, enabling control over their morphology, growth and size.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"80 ","pages":"Pages 182-193"},"PeriodicalIF":3.1000,"publicationDate":"2025-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Current Applied Physics","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S156717392500197X","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The atmospheric pressure chemical vapor deposition (APCVD) synthesis of high-quality 2D WS2 (tungsten disulfide) critically depends on the precise timing of sulfur vapor introduction. This study investigates the role of sulfur-rich environment and growth time on the surface morphology of 2D WS2 films on the silicon substrate. Three different varying sets of parameters, designated as SP1, SP2, and SP3, were examined to optimize the time of sulfur vapor introduction. This process enabled the formation of large mono- and bi-layer triangular islands, with flake sizes ranging from ∼70 to 164 μm, as well as long few-layer structures. The atomically thin WS2 exhibited strong photoluminescence (PL) at ∼1.93 eV, with a ∼70-fold enhancement and a full-width at half maximum (FWHM) of ∼12 nm. The optimized SP3 parameters were applied using the sapphire substrate, and the results were consistent. Thus, this study highlights the crucial role of sulfur vapor synchronization in WS2 synthesis, enabling control over their morphology, growth and size.
期刊介绍:
Current Applied Physics (Curr. Appl. Phys.) is a monthly published international journal covering all the fields of applied science investigating the physics of the advanced materials for future applications.
Other areas covered: Experimental and theoretical aspects of advanced materials and devices dealing with synthesis or structural chemistry, physical and electronic properties, photonics, engineering applications, and uniquely pertinent measurement or analytical techniques.
Current Applied Physics, published since 2001, covers physics, chemistry and materials science, including bio-materials, with their engineering aspects. It is a truly interdisciplinary journal opening a forum for scientists of all related fields, a unique point of the journal discriminating it from other worldwide and/or Pacific Rim applied physics journals.
Regular research papers, letters and review articles with contents meeting the scope of the journal will be considered for publication after peer review.
The Journal is owned by the Korean Physical Society.