Visible Light-Promoted Aerobic Oxidation of Boronic Acids and Esters Utilizing a Benzothioxanthene Imide as the Photocatalyst

IF 2.7 3区化学 Q2 CHEMISTRY, ORGANIC

European Journal of Organic Chemistry Pub Date : 2025-09-27 DOI:10.1002/ejoc.202500782

Stamatis K. Serviou, Petros L. Gkizis, Darío Puchán Sánchez, Soussana Azar, Arthur H. G. David, Clement Cabanetos, Christoforos G. Kokotos

引用次数: 0

Abstract

Herein, a sustainable and eco-friendly protocol is reported for the aerobic photochemical oxidation of boronic acids or esters, utilizing a dibenzothioxanthene imide as the photocatalyst at a very low catalyst loading (0.01%) in 2-propanol, employing a 456 nm irradiation source. Additionally, this protocol is successfully applied to a variety of substrates.

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以苯并噻吩亚胺为光催化剂，可见光促进硼酸和硼酸酯的好氧氧化

本文报道了一种可持续和环保的硼酸或酯的有氧光化学氧化方案，利用二苯并噻吩亚胺作为光催化剂，在2-丙醇中以极低的催化剂负载（0.01%），采用456nm辐照源。此外，该协议成功地应用于各种基材。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

European Journal of Organic Chemistry 化学-有机化学

CiteScore

5.40

自引率

3.60%

发文量

752

审稿时长

1 months

期刊介绍： The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.