Perovskite Oxide LaFeO3 Hollow Microspheres for Highly Sensitive and Selective Detection of Li-Ion Battery Electrolyte (DMC) Leakage.

IF 9.1 1区化学 Q1 CHEMISTRY, ANALYTICAL

ACS Sensors Pub Date : 2025-09-27 DOI:10.1021/acssensors.5c02322

Chaoqi Zhu,Kechen Zhou,Huiyu Su,Yazhou Yang,Jiahong Tang,Xiaoxia Wang,Wulin Song,Dawen Zeng

{"title":"Perovskite Oxide LaFeO3 Hollow Microspheres for Highly Sensitive and Selective Detection of Li-Ion Battery Electrolyte (DMC) Leakage.","authors":"Chaoqi Zhu,Kechen Zhou,Huiyu Su,Yazhou Yang,Jiahong Tang,Xiaoxia Wang,Wulin Song,Dawen Zeng","doi":"10.1021/acssensors.5c02322","DOIUrl":null,"url":null,"abstract":"The development of highly sensitive electrolyte leakage monitoring sensors is critical for enabling early fault detection and ensuring the safe operation of lithium-ion battery (LIBs) systems. In this study, perovskite LaFeO3 hollow microspheres with an average diameter of 850 nm were synthesized via a hydrothermal method. Gas-sensing tests demonstrated that the LaFeO3 hollow microsphere sensor exhibited exceptional responsiveness to dimethyl carbonate (DMC) gas, achieving a remarkable response value of 67.9 toward 10 ppm DMC at an operating temperature of 150 °C. The sensor also showed a fast response/recovery rate (170/90 s), excellent selectivity, long-term stability, and a low detection limit of 20 ppb. This excellent gas-sensing performance may be attributed to the high specific surface area and well-developed mesoporous structure of the hollow structure. Moreover, it demonstrated rapid response capabilities in simulated leakage detection scenarios. This work presents a novel perovskite LaFeO3-based sensor that can effectively detect DMC gas leakage and provide an effective strategy for enhancing safety monitoring in LIB applications.","PeriodicalId":24,"journal":{"name":"ACS Sensors","volume":"26 1","pages":""},"PeriodicalIF":9.1000,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Sensors","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acssensors.5c02322","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}

引用次数: 0

Abstract

The development of highly sensitive electrolyte leakage monitoring sensors is critical for enabling early fault detection and ensuring the safe operation of lithium-ion battery (LIBs) systems. In this study, perovskite LaFeO3 hollow microspheres with an average diameter of 850 nm were synthesized via a hydrothermal method. Gas-sensing tests demonstrated that the LaFeO3 hollow microsphere sensor exhibited exceptional responsiveness to dimethyl carbonate (DMC) gas, achieving a remarkable response value of 67.9 toward 10 ppm DMC at an operating temperature of 150 °C. The sensor also showed a fast response/recovery rate (170/90 s), excellent selectivity, long-term stability, and a low detection limit of 20 ppb. This excellent gas-sensing performance may be attributed to the high specific surface area and well-developed mesoporous structure of the hollow structure. Moreover, it demonstrated rapid response capabilities in simulated leakage detection scenarios. This work presents a novel perovskite LaFeO3-based sensor that can effectively detect DMC gas leakage and provide an effective strategy for enhancing safety monitoring in LIB applications.

查看原文本刊更多论文

钙钛矿氧化物LaFeO3空心微球用于高灵敏度和选择性检测锂离子电池电解液（DMC）泄漏。

开发高灵敏度的电解液泄漏监测传感器对于实现早期故障检测和确保锂离子电池（LIBs）系统的安全运行至关重要。本研究采用水热法制备了平均直径为850 nm的钙钛矿LaFeO3空心微球。气敏测试表明，LaFeO3空心微球传感器对碳酸二甲酯（DMC）气体表现出优异的响应性，在150℃的工作温度下，对10 ppm DMC的响应值达到了67.9。该传感器还具有快速的响应/回收率（170/90 s），出色的选择性，长期稳定性和低检测限（20 ppb）。这种优异的气敏性能可能归因于中空结构的高比表面积和发育良好的介孔结构。此外，它在模拟泄漏检测场景中展示了快速响应能力。本研究提出了一种新型的基于钙钛矿lafeo3的传感器，可以有效地检测DMC气体泄漏，并为LIB应用中的安全监测提供了有效的策略。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

ACS Sensors Chemical Engineering-Bioengineering

CiteScore

14.50

自引率

3.40%

发文量

372

期刊介绍： ACS Sensors is a peer-reviewed research journal that focuses on the dissemination of new and original knowledge in the field of sensor science, particularly those that selectively sense chemical or biological species or processes. The journal covers a broad range of topics, including but not limited to biosensors, chemical sensors, gas sensors, intracellular sensors, single molecule sensors, cell chips, and microfluidic devices. It aims to publish articles that address conceptual advances in sensing technology applicable to various types of analytes or application papers that report on the use of existing sensing concepts in new ways or for new analytes.