Core and End-Capped Engineering as a Powerful Tool in the Search of Long-Term High-Performance Dye-Sensitized Solar Cells.

IF 6.6 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
ChemSusChem Pub Date : 2025-09-26 DOI:10.1002/cssc.202501564
Matías J Alonso-Navarro, Santiago Franco, Fátima Suárez-Blas, Raquel Andreu, Jesús Orduna, M Mar Ramos, José L Segura
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引用次数: 0

Abstract

In the search of new electroactive organic dyes in dye-sensitized solar cells technology, a series of D-π-A assemblies, named as TA-BTD-CNCOOH, OMeTA-BTD-CNCOOH, TA-Y6-CNCOOH, and OMeTA-Y6-CNCOOH is rationally designed and synthesized, in which precise modifications have been carried out in order to obtain structure-performance relations in the field of dye-sensitized solar cells. After careful evaluation of the photophysical and electrochemical properties of these semiconductors, these systems are applied as active materials, showing high performance with power conversion efficiency maximum values of 9.05% and 18.5% for outdoor and indoor conditions, respectively. In addition, the best material of these organic architectures, TA-BTD-CNCOOH, shows an excellent long-term stability, up to 3,360 h, with no significant variance in its performance over time.

核心和端盖工程是寻找长期高性能染料敏化太阳能电池的有力工具。
为了在染料敏化太阳能电池技术中寻找新的电活性有机染料,合理设计合成了一系列D-π-A复合物,分别命名为TA-BTD-CNCOOH、OMeTA-BTD-CNCOOH、TA-Y6-CNCOOH和OMeTA-Y6-CNCOOH,并对其进行了精确修饰,以期获得染料敏化太阳能电池领域的结构-性能关系。在仔细评估了这些半导体的光物理和电化学性能后,将这些系统作为活性材料应用,在室外和室内条件下,这些系统的功率转换效率分别高达9.05%和18.5%。此外,这些有机结构中最好的材料TA-BTD-CNCOOH表现出优异的长期稳定性,长达3,360小时,其性能随时间的变化没有显着变化。
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来源期刊
ChemSusChem
ChemSusChem 化学-化学综合
CiteScore
15.80
自引率
4.80%
发文量
555
审稿时长
1.8 months
期刊介绍: ChemSusChem Impact Factor (2016): 7.226 Scope: Interdisciplinary journal Focuses on research at the interface of chemistry and sustainability Features the best research on sustainability and energy Areas Covered: Chemistry Materials Science Chemical Engineering Biotechnology
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