Janus Particle Sizing Agent for Interfacial Enhancement of Basalt Fiber/Poly(vinyl chloride) Composites

IF 4 2区 化学 Q2 POLYMER SCIENCE
Tian-Lin Liu, Peng Kang, Hui Wang, Da-Li Gao, Kai Xu, Tao Cai, Qi Xin, Sheng-Peng Shi, Na Wang, Fu-Xin Liang
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引用次数: 0

Abstract

Sizing treatment is a suitable technique to modify the fiber-matrix interfaces without damage of inherent performance of fibers. In this work, sizing agents based on Janus particles (JPs) were utilized to enhance the interface of basalt fiber (BF)/poly(vinyl chloride) (PVC) composites. polystyrene/poly(butyl acrylate) (PS/PBA)@silica JPs were synthesized by seed emulsion polymerization and three different sizing agents were prepared for BF sizing treatment. JPs with organic soft sphere and inorganic hard hemisphere enhanced the interfaces through their amphiphilicity, chemical bonding and mechanical interlock. The mechanical properties of composite with JPs sizing treated BFs performed better when there was one JPs layer modified on the interface. According to the intermitting bonding and gradient modulus theory, JPs patterned interfaces are ideal transition layers between high modulus BF and low modulus PVC.

用于玄武岩纤维/聚氯乙烯复合材料界面增强的Janus颗粒施胶剂
施胶处理是在不损害纤维固有性能的前提下对纤维-基体界面进行改性的一种合适的技术。研究了基于Janus颗粒(JPs)的施胶剂对玄武岩纤维(BF)/聚氯乙烯(PVC)复合材料界面的增强作用。采用种子乳液聚合法制备了聚苯乙烯/聚丙烯酸丁酯(PS/PBA)@二氧化硅JPs,并制备了3种不同的施胶剂进行高炉施胶处理。具有有机软球和无机硬半球的jp通过其两亲性、化学键和机械互锁增强了界面。当界面上只添加一层改性的JPs层时,经过JPs上浆处理的BFs复合材料的力学性能更好。根据间断键合和梯度模量理论,JPs图纹界面是高模量BF和低模量PVC之间的理想过渡层。
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来源期刊
Chinese Journal of Polymer Science
Chinese Journal of Polymer Science 化学-高分子科学
CiteScore
7.10
自引率
11.60%
发文量
218
审稿时长
6.0 months
期刊介绍: Chinese Journal of Polymer Science (CJPS) is a monthly journal published in English and sponsored by the Chinese Chemical Society and the Institute of Chemistry, Chinese Academy of Sciences. CJPS is edited by a distinguished Editorial Board headed by Professor Qi-Feng Zhou and supported by an International Advisory Board in which many famous active polymer scientists all over the world are included. The journal was first published in 1983 under the title Polymer Communications and has the current name since 1985. CJPS is a peer-reviewed journal dedicated to the timely publication of original research ideas and results in the field of polymer science. The issues may carry regular papers, rapid communications and notes as well as feature articles. As a leading polymer journal in China published in English, CJPS reflects the new achievements obtained in various laboratories of China, CJPS also includes papers submitted by scientists of different countries and regions outside of China, reflecting the international nature of the journal.
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