Additive engineering leads to stable halide perovskite with bipolar resistive switching behavior

IF 2.6 4区材料科学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Journal of Nanoparticle Research Pub Date : 2025-07-19 DOI:10.1007/s11051-025-06400-4

Qi Bu, Zhen Fan, Xingyu Liu, Zhijie Luo, Yuhui Zheng, Qianming Wang

{"title":"Additive engineering leads to stable halide perovskite with bipolar resistive switching behavior","authors":"Qi Bu, Zhen Fan, Xingyu Liu, Zhijie Luo, Yuhui Zheng, Qianming Wang","doi":"10.1007/s11051-025-06400-4","DOIUrl":null,"url":null,"abstract":"<div>Halide perovskites have been considered as promising candidates for nonvolatile memory systems, but the specific study of structure–property relationship for such flexible framework is far from satisfied. The employment of bismuth avoids the toxicity of lead and instability of APbX3 structure, a new model of Cs3Bi2Br9 has been developed. The well control of crystal defects is achieved by the addition of low-molecular-weight molecule (citric acid (CA)) during solution phase synthesis. The switching window and device performance are further improved by incorporating Poly(methyl methacrylate) (PMMA) into the perovskite layer. Through synergistic additives treatment, the devices demonstrate bipolar resistive switching behavior with low operating voltages (± 0.6 V), significant ON/OFF ratio (104), stable cyclic retention (600 cycles), and prolonged retention times (> 300 s). These results offer new insights for the design of lead-free perovskite memory devices and will be beneficial to optimize the operating processes.</div>","PeriodicalId":653,"journal":{"name":"Journal of Nanoparticle Research","volume":"27 8","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2025-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Nanoparticle Research","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11051-025-06400-4","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

Halide perovskites have been considered as promising candidates for nonvolatile memory systems, but the specific study of structure–property relationship for such flexible framework is far from satisfied. The employment of bismuth avoids the toxicity of lead and instability of APbX₃ structure, a new model of Cs₃Bi₂Br₉ has been developed. The well control of crystal defects is achieved by the addition of low-molecular-weight molecule (citric acid (CA)) during solution phase synthesis. The switching window and device performance are further improved by incorporating Poly(methyl methacrylate) (PMMA) into the perovskite layer. Through synergistic additives treatment, the devices demonstrate bipolar resistive switching behavior with low operating voltages (± 0.6 V), significant ON/OFF ratio (10⁴), stable cyclic retention (600 cycles), and prolonged retention times (> 300 s). These results offer new insights for the design of lead-free perovskite memory devices and will be beneficial to optimize the operating processes.

查看原文本刊更多论文

添加剂工程导致具有双极电阻开关行为的稳定卤化物钙钛矿

卤化物钙钛矿被认为是非易失性存储系统的有前途的候选者，但对这种柔性框架的结构-性能关系的具体研究还远远没有得到满足。铋的使用避免了铅的毒性和APbX3结构的不稳定性，开发了一种新的Cs3Bi2Br9模型。通过在固相合成过程中加入低分子量分子（柠檬酸），实现了对晶体缺陷的良好控制。通过将聚甲基丙烯酸甲酯（PMMA）掺入钙钛矿层，进一步改善了开关窗口和器件性能。通过增效添加剂处理，器件具有低工作电压（±0.6 V）、显著的开/关比（104）、稳定的循环保持（600个循环）和延长的保持时间（> 300 s）的双极电阻开关行为。这些结果为无铅钙钛矿存储器件的设计提供了新的见解，并将有利于优化操作过程。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of Nanoparticle Research 工程技术-材料科学：综合

CiteScore

4.40

自引率

4.00%

发文量

198

审稿时长

3.9 months

期刊介绍： The objective of the Journal of Nanoparticle Research is to disseminate knowledge of the physical, chemical and biological phenomena and processes in structures that have at least one lengthscale ranging from molecular to approximately 100 nm (or submicron in some situations), and exhibit improved and novel properties that are a direct result of their small size. Nanoparticle research is a key component of nanoscience, nanoengineering and nanotechnology. The focus of the Journal is on the specific concepts, properties, phenomena, and processes related to particles, tubes, layers, macromolecules, clusters and other finite structures of the nanoscale size range. Synthesis, assembly, transport, reactivity, and stability of such structures are considered. Development of in-situ and ex-situ instrumentation for characterization of nanoparticles and their interfaces should be based on new principles for probing properties and phenomena not well understood at the nanometer scale. Modeling and simulation may include atom-based quantum mechanics; molecular dynamics; single-particle, multi-body and continuum based models; fractals; other methods suitable for modeling particle synthesis, assembling and interaction processes. Realization and application of systems, structures and devices with novel functions obtained via precursor nanoparticles is emphasized. Approaches may include gas-, liquid-, solid-, and vacuum-based processes, size reduction, chemical- and bio-self assembly. Contributions include utilization of nanoparticle systems for enhancing a phenomenon or process and particle assembling into hierarchical structures, as well as formulation and the administration of drugs. Synergistic approaches originating from different disciplines and technologies, and interaction between the research providers and users in this field, are encouraged.