Identification of Turmeric and Revelation of Adulterations by Digital Colorimetry and Near-IR Spectrometry

IF 1.1 4区 化学 Q4 CHEMISTRY, ANALYTICAL
O. E. Emel’yanov, V. G. Amelin, A. V. Tret’yakov
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引用次数: 0

Abstract

A possibility of identifying turmeric and establishing its adulterations by simple and available methods using IR spectrometry, digital colorimetry, and chemometric spectral data processing is shown. Near-IR spectrometry enabled the differentiation of samples of turmeric powder purchased in India and prepared by grinding roots and commercial samples, and also their distinguishing from samples containing flour, starch, bread crumb, and chalk impurities by analyzing diffuse reflection spectra using principal component analysis, hierarchical cluster analysis, and soft independent modelling of class analogy. The same approaches were applied to a simpler and a less expensive colorimetry method. Chemometric processing of the data obtained confirmed the absence of similarity between the analyzed turmeric samples and samples with additives and made it possible to determine impurities using multivariate regression analysis algorithms. A comparison of the results obtained by IR spectrometry and digital colorimetry demonstrated their equivalent efficiency, so that a more available colorimetry method can be recommended for the routine quality control and the detection of turmeric adulterations.

Abstract Image

数字比色法和近红外光谱法鉴别姜黄及其掺假成分
利用红外光谱法、数字比色法和化学计量光谱数据处理等简单可行的方法,鉴别姜黄并确定其掺假的可能性。近红外光谱分析可以区分从印度购买的姜黄粉和商业样品,并通过主成分分析、层次聚类分析和类类比的软独立建模来分析漫反射光谱,从而区分含有面粉、淀粉、面包屑和白垩杂质的样品。同样的方法被应用于一种更简单、更便宜的比色法。对所得数据的化学计量学处理证实了所分析的姜黄样品与添加添加剂的样品之间没有相似性,并且可以使用多元回归分析算法确定杂质。通过对红外光谱法和数字比色法测定结果的比较,证明了两者的效率相当,从而为姜黄掺假品的常规质量控制和检测推荐一种更有效的比色法。
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来源期刊
Journal of Analytical Chemistry
Journal of Analytical Chemistry 化学-分析化学
CiteScore
2.10
自引率
9.10%
发文量
146
审稿时长
13 months
期刊介绍: The Journal of Analytical Chemistry is an international peer reviewed journal that covers theoretical and applied aspects of analytical chemistry; it informs the reader about new achievements in analytical methods, instruments and reagents. Ample space is devoted to problems arising in the analysis of vital media such as water and air. Consideration is given to the detection and determination of metal ions, anions, and various organic substances. The journal welcomes manuscripts from all countries in the English or Russian language.
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