Innovations in Advanced Material Design for Enhancing Stability In Perovskites Solar Cells

IF 3.3 3区 材料科学 Q3 CHEMISTRY, PHYSICAL
Silicon Pub Date : 2025-04-05 DOI:10.1007/s12633-025-03314-7
Praveen Barmavatu, Baburao Gaddala, Dadapeer Doddamani, Sharun Mendonca, Jatoth Heeraman, Ramalinga Viswanathan Mangalaraja
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引用次数: 0

Abstract

The pursuit of sustainable energy solutions has intensified the need for innovative materials for solar technology, particularly in the development of perovskite solar cells (PSCs). One primary issue is the inherent sensitivity of perovskite materials to environmental factors such as moisture, oxygen, and light, which can lead to degradation and reduced efficiency over time. The objective of this study is to explore and develop innovative advanced materials that enhance the stability and longevity of perovskite solar cells. This study presents a comprehensive investigation into the selection and characterization of semiconductor materials for photovoltaic applications, focusing on perovskites, silicon, and organic photovoltaics to analyze their optical and electronic properties. It further explores innovative device fabrication and optimization strategies, particularly through layer stacking design and tandem solar cell configurations aimed to enhance light absorption and charge transport efficiency. The research incorporates the use of transparent conductive oxides (TCOs), hole transport materials (HTMs), and electron transport materials (ETMs) to optimize the device's performance. The performance evaluation and stability testing are rigorously conducted, utilizing current–voltage (I-V) measurements under Standard Test Conditions (STC) to assess the efficiency and fill factor of solar cells. The findings show that the vapour deposition boasts the highest average efficiency at 24.0%, enabling precise control over film thickness and composition, which enhances material properties, and Recent advancements in photovoltaic technology have achieved a 28.3% efficiency in high-performance solar cells, significantly surpassing earlier mid-20 s efficiency. However, stability remains a challenge, with current stability at 26%, highlighting the need for long-term reliability in real-world conditions implemented by using MATLAB software. Future research could focus on next-generation hybrid materials, such as combining organic–inorganic perovskites with 2D materials or graphene oxide to enhance stability and performance. These innovative hybrids may improve charge transport, reduce degradation, and provide better thermal and environmental stability, leading to more durable and efficient perovskite solar cells.

提高钙钛矿太阳能电池稳定性的先进材料设计创新
对可持续能源解决方案的追求加剧了对太阳能技术创新材料的需求,特别是在钙钛矿太阳能电池(PSCs)的开发中。一个主要问题是钙钛矿材料对环境因素(如水分、氧气和光线)的固有敏感性,这可能导致降解和随着时间的推移效率降低。这项研究的目的是探索和开发创新的先进材料,提高钙钛矿太阳能电池的稳定性和寿命。本研究对光伏应用半导体材料的选择和特性进行了全面的研究,重点研究了钙钛矿、硅和有机光伏材料,分析了它们的光学和电子特性。它进一步探索了创新的器件制造和优化策略,特别是通过层堆叠设计和串联太阳能电池配置,旨在提高光吸收和电荷传输效率。该研究结合了透明导电氧化物(TCOs)、空穴传输材料(HTMs)和电子传输材料(ETMs)的使用,以优化器件的性能。性能评估和稳定性测试严格进行,利用标准测试条件(STC)下的电流-电压(I-V)测量来评估太阳能电池的效率和填充系数。研究结果表明,气相沉积的平均效率最高,达到24.0%,可以精确控制薄膜厚度和成分,从而提高材料性能。最近光伏技术的进步使高性能太阳能电池的效率达到28.3%,大大超过了20世纪20年代中期的效率。然而,稳定性仍然是一个挑战,目前的稳定性为26%,突出了使用MATLAB软件实现现实条件下长期可靠性的需求。未来的研究可能会集中在下一代混合材料上,比如将有机-无机钙钛矿与二维材料或氧化石墨烯结合起来,以提高稳定性和性能。这些创新的混合可能会改善电荷传输,减少降解,并提供更好的热稳定性和环境稳定性,从而产生更耐用和高效的钙钛矿太阳能电池。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Silicon
Silicon CHEMISTRY, PHYSICAL-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
5.90
自引率
20.60%
发文量
685
审稿时长
>12 weeks
期刊介绍: The journal Silicon is intended to serve all those involved in studying the role of silicon as an enabling element in materials science. There are no restrictions on disciplinary boundaries provided the focus is on silicon-based materials or adds significantly to the understanding of such materials. Accordingly, such contributions are welcome in the areas of inorganic and organic chemistry, physics, biology, engineering, nanoscience, environmental science, electronics and optoelectronics, and modeling and theory. Relevant silicon-based materials include, but are not limited to, semiconductors, polymers, composites, ceramics, glasses, coatings, resins, composites, small molecules, and thin films.
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