Substrate-dependent properties of PECVD-deposited diamond-like carbon films: structural, morphological, and mechanical insights

IF 2.6 4区 材料科学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Mohd Sarim Khan, Lokendra Kumar Katiyar, Manish Kumar, C. Sasikumar
{"title":"Substrate-dependent properties of PECVD-deposited diamond-like carbon films: structural, morphological, and mechanical insights","authors":"Mohd Sarim Khan,&nbsp;Lokendra Kumar Katiyar,&nbsp;Manish Kumar,&nbsp;C. Sasikumar","doi":"10.1007/s11051-025-06409-9","DOIUrl":null,"url":null,"abstract":"<div><p>This study examines the influence of different substrate materials on the structural, mechanical, and hydrophobic properties of diamond-like carbon (DLC) films deposited using the PECVD technique. Substrates including stainless steel, silicon, Silica, and epoxy chip material were investigated to understand their impact on the performance of DLC coatings. Raman, FTIR spectroscopy and XPS revealed substrate-dependent variations in bonding configurations, with stainless steel exhibiting prominent sp2 clustering and graphitization, while Silica displayed a predominantly amorphous structure with enhanced sp3 content. Silicon demonstrated superior mechanical properties, attributed to its hexagonal DLC morphology and higher sp3 bonding, making it ideal for demanding applications. Epoxy chip material, characterized by a globular DLC structure and higher sp2 content, exhibited lower mechanical performance but moderate hydrophobicity. Silica was identified as the most hydrophobic substrate, followed by silicon, epoxy chip, and stainless steel. These findings underscore the importance of substrate characteristics and structural tailoring in optimizing DLC coatings for diverse industrial applications, including protective, tribological, and water-repellent surfaces.</p></div>","PeriodicalId":653,"journal":{"name":"Journal of Nanoparticle Research","volume":"27 8","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2025-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Nanoparticle Research","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11051-025-06409-9","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

This study examines the influence of different substrate materials on the structural, mechanical, and hydrophobic properties of diamond-like carbon (DLC) films deposited using the PECVD technique. Substrates including stainless steel, silicon, Silica, and epoxy chip material were investigated to understand their impact on the performance of DLC coatings. Raman, FTIR spectroscopy and XPS revealed substrate-dependent variations in bonding configurations, with stainless steel exhibiting prominent sp2 clustering and graphitization, while Silica displayed a predominantly amorphous structure with enhanced sp3 content. Silicon demonstrated superior mechanical properties, attributed to its hexagonal DLC morphology and higher sp3 bonding, making it ideal for demanding applications. Epoxy chip material, characterized by a globular DLC structure and higher sp2 content, exhibited lower mechanical performance but moderate hydrophobicity. Silica was identified as the most hydrophobic substrate, followed by silicon, epoxy chip, and stainless steel. These findings underscore the importance of substrate characteristics and structural tailoring in optimizing DLC coatings for diverse industrial applications, including protective, tribological, and water-repellent surfaces.

pecvd沉积的类金刚石碳膜的衬底依赖性质:结构、形态和力学见解
本研究考察了不同的衬底材料对采用PECVD技术沉积的类金刚石碳(DLC)薄膜的结构、力学和疏水性的影响。研究了不锈钢、硅、二氧化硅和环氧切屑材料等基材,以了解它们对DLC涂层性能的影响。拉曼光谱、FTIR光谱和XPS光谱显示出了与基体相关的键合结构变化,不锈钢表现出明显的sp2簇化和石墨化,而二氧化硅则表现出主要的非晶态结构,sp3含量增加。硅表现出优异的机械性能,由于其六边形DLC形态和更高的sp3键合,使其成为要求苛刻的应用的理想选择。环氧切屑材料具有球形DLC结构和较高的sp2含量,其力学性能较低,但疏水性适中。二氧化硅被认为是最疏水的衬底,其次是硅、环氧片和不锈钢。这些发现强调了基材特性和结构定制对优化DLC涂层的重要性,这些涂层适用于各种工业应用,包括防护、摩擦学和防水表面。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Journal of Nanoparticle Research
Journal of Nanoparticle Research 工程技术-材料科学:综合
CiteScore
4.40
自引率
4.00%
发文量
198
审稿时长
3.9 months
期刊介绍: The objective of the Journal of Nanoparticle Research is to disseminate knowledge of the physical, chemical and biological phenomena and processes in structures that have at least one lengthscale ranging from molecular to approximately 100 nm (or submicron in some situations), and exhibit improved and novel properties that are a direct result of their small size. Nanoparticle research is a key component of nanoscience, nanoengineering and nanotechnology. The focus of the Journal is on the specific concepts, properties, phenomena, and processes related to particles, tubes, layers, macromolecules, clusters and other finite structures of the nanoscale size range. Synthesis, assembly, transport, reactivity, and stability of such structures are considered. Development of in-situ and ex-situ instrumentation for characterization of nanoparticles and their interfaces should be based on new principles for probing properties and phenomena not well understood at the nanometer scale. Modeling and simulation may include atom-based quantum mechanics; molecular dynamics; single-particle, multi-body and continuum based models; fractals; other methods suitable for modeling particle synthesis, assembling and interaction processes. Realization and application of systems, structures and devices with novel functions obtained via precursor nanoparticles is emphasized. Approaches may include gas-, liquid-, solid-, and vacuum-based processes, size reduction, chemical- and bio-self assembly. Contributions include utilization of nanoparticle systems for enhancing a phenomenon or process and particle assembling into hierarchical structures, as well as formulation and the administration of drugs. Synergistic approaches originating from different disciplines and technologies, and interaction between the research providers and users in this field, are encouraged.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信