Joseph Frederick Thuma, Carl Henry Fleischer III, Frédéric Perras, Rana Biswas, Levi Stanley, Wenyu Huang
{"title":"Boron Monoxide is a One-Dimensional Polymer","authors":"Joseph Frederick Thuma, Carl Henry Fleischer III, Frédéric Perras, Rana Biswas, Levi Stanley, Wenyu Huang","doi":"10.1039/d5cc04723d","DOIUrl":null,"url":null,"abstract":"It was recently reported that boron monoxide (BO) is formed through the cross-linking of B4O2 structural building units. Multiple theoretical phases agree with this description. Using pycnometry, multidimensional 17O NMR spectroscopy, and plane-wave DFT calculations we determined the likely polymorph to be a one-dimensional polymer initially proposed in 1955.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"28 1","pages":""},"PeriodicalIF":4.2000,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5cc04723d","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
It was recently reported that boron monoxide (BO) is formed through the cross-linking of B4O2 structural building units. Multiple theoretical phases agree with this description. Using pycnometry, multidimensional 17O NMR spectroscopy, and plane-wave DFT calculations we determined the likely polymorph to be a one-dimensional polymer initially proposed in 1955.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.