Cover Feature: Small Molecule Activation by Metallylenes and their Follow-Up Reactions (ChemistryEurope 5/2025)

ChemistryEurope Pub Date : 2025-09-23 DOI:10.1002/ceur.70079
Eveline H. Tiekink, Matthijs W. Kragtwijk, Trevor A. Hamlin
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Abstract

Blurring the boundaries between main-group and transition metal chemistry, Group 14 metallylenes offer a tunable, earth-abundant platform for catalysis. Once the domain of d-block elements, transition metal-like reactivity is now within reach—unlocking new avenues for sustainable small-molecule activation and follow-up reactions through ligand optimization and quantum chemical design. More information can be found in the Review by T. A. Hamlin and co-workers (DOI: 10.1002/ceur.202500119).

Abstract Image

封面专题:小分子的聚乙烯活化及其后续反应(ChemistryEurope 5/2025)
模糊了主族和过渡金属化学之间的界限,14族金属为催化提供了一个可调的、地球丰富的平台。一旦d块元素的域,过渡金属样的反应性现在是触手可及的-通过配体优化和量子化学设计为可持续的小分子激活和后续反应打开了新的途径。更多信息可以在t.a. Hamlin及其同事的综述中找到(DOI: 10.1002/ceur.202500119)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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