Structural and electronic tuning of hybrid metal thiocyanate N-oxides.

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-09-24 DOI:10.1039/d5dt02188j

Grace M Robertson,Adam Jaffe

引用次数: 0

Abstract

Hybrid metal thiocyanates are highly tailorable materials isolable under mild synthetic conditions. By varying pyridine-N-oxide derivatives within manganese, cobalt, and nickel congeners, we show fine-tuning of structural and electronic features depending on molecular substituent and metal selection, providing a roadmap for application-specific customization and potential property-tuning.

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杂化金属硫氰酸盐n -氧化物的结构和电子调谐。

杂化金属硫氰酸酯是一种在温和的合成条件下可分离的高度可定制的材料。通过改变锰、钴和镍同族物中的吡啶- n-氧化物衍生物，我们展示了基于分子取代基和金属选择的结构和电子特征微调，为特定应用的定制和潜在的性能调整提供了路线图。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.