{"title":"Pore-Engineered Carbon Cloth via Thermal Activation for Shuttle-Free Zinc-Iodine Batteries with Ultralow Self-Discharge.","authors":"Ping Wu, Hongli Lin, Qinghua Wang","doi":"10.1002/cssc.202501455","DOIUrl":null,"url":null,"abstract":"<p><p>Zinc-iodine (Zn-I<sub>2</sub>) batteries are promising for grid-scale energy storage but suffer from severe polyiodide shuttling and rapid self-discharge. Here, a thermally activated carbon cloth (CC450) that simultaneously addresses iodine confinement and reaction kinetics through precisely engineered hierarchical porosity is reported. By optimizing oxidative calcination at 450 °C in air, CC450 develops a unique pore structure with nanopores for strong I<sub>3</sub> <sup>-</sup> adsorption and interconnected macropores for rapid ion transport, while maintaining the intrinsic conductivity and flexibility of CC. The CC450 cathode achieves an exceptional balance of performance metrics: high areal capacity, ultralow self-discharge (3.05% in 24 h), and outstanding cycling stability (94.63% capacity retention over 1000 cycles), which represents the best-reported performance for binder-free carbon electrodes in Zn-I<sub>2</sub> batteries. Mechanistic studies reveal that CC450's 12-fold reduction in charge-transfer resistance and low activation energy for I<sup>-</sup> oxidation stem from its optimal surface chemistry and pore hierarchy. The self-discharge tests and UV-vis spectroscopy confirm efficient iodine shuttle suppression. Unlike complex nanomaterial-based hosts, CC450 is fabricated through a scalable ambient-air process, offering immediate industrial relevance. This work provides critical insights into pore-engineered carbon hosts for metal-iodine batteries and establishes a generalizable strategy for achieving high-energy, long-life energy storage systems.</p>","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":" ","pages":"e202501455"},"PeriodicalIF":6.6000,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemSusChem","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/cssc.202501455","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Zinc-iodine (Zn-I2) batteries are promising for grid-scale energy storage but suffer from severe polyiodide shuttling and rapid self-discharge. Here, a thermally activated carbon cloth (CC450) that simultaneously addresses iodine confinement and reaction kinetics through precisely engineered hierarchical porosity is reported. By optimizing oxidative calcination at 450 °C in air, CC450 develops a unique pore structure with nanopores for strong I3- adsorption and interconnected macropores for rapid ion transport, while maintaining the intrinsic conductivity and flexibility of CC. The CC450 cathode achieves an exceptional balance of performance metrics: high areal capacity, ultralow self-discharge (3.05% in 24 h), and outstanding cycling stability (94.63% capacity retention over 1000 cycles), which represents the best-reported performance for binder-free carbon electrodes in Zn-I2 batteries. Mechanistic studies reveal that CC450's 12-fold reduction in charge-transfer resistance and low activation energy for I- oxidation stem from its optimal surface chemistry and pore hierarchy. The self-discharge tests and UV-vis spectroscopy confirm efficient iodine shuttle suppression. Unlike complex nanomaterial-based hosts, CC450 is fabricated through a scalable ambient-air process, offering immediate industrial relevance. This work provides critical insights into pore-engineered carbon hosts for metal-iodine batteries and establishes a generalizable strategy for achieving high-energy, long-life energy storage systems.
期刊介绍:
ChemSusChem
Impact Factor (2016): 7.226
Scope:
Interdisciplinary journal
Focuses on research at the interface of chemistry and sustainability
Features the best research on sustainability and energy
Areas Covered:
Chemistry
Materials Science
Chemical Engineering
Biotechnology