Real-space observation of salt-dependent aging in LAPONITE® gels.

IF 2.8 3区 化学 Q3 CHEMISTRY, PHYSICAL
Soft Matter Pub Date : 2025-09-23 DOI:10.1039/d5sm00603a
Shunichi Saito, Sooyeon Kim, Yuichi Taniguchi, Miho Yanagisawa
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引用次数: 0

Abstract

Colloidal gels gradually evolve as their structures reorganize, a process known as aging. Understanding this behavior is essential for fundamental science and practical applications such as drug delivery and tissue engineering. This study examines the aging of low-concentration LAPONITE® suspensions with varying salt concentrations using fluorescence microscopy, scattering imaging, and particle tracking microrheology. Structural heterogeneity appeared earlier at higher salt concentrations, and the average size of aggregates decreased as the salt concentration increased further. Fourier transform analysis corroborated these trends, and scattering images showed similar results. Microrheology revealed distinct dynamics in LAPONITE®-rich and LAPONITE®-poor regions: the poor phase exhibited liquid-like behavior, while the rich phase exhibited gel-like properties. Further analysis suggested the presence of submicron or nanoscale structural heterogeneities within the rich phase. These findings provide insight into how aging and salt concentration shape the structure and dynamics of colloidal gels.

LAPONITE®凝胶盐依赖性老化的实空间观察
胶体随着结构的重组而逐渐进化,这一过程被称为老化。了解这种行为对基础科学和实际应用(如药物输送和组织工程)至关重要。本研究使用荧光显微镜、散射成像和颗粒跟踪微流变学检测不同盐浓度的低浓度LAPONITE®悬浮液的老化。随着盐浓度的增加,团聚体的平均粒径逐渐减小。傅里叶变换分析证实了这些趋势,散射图像也显示了类似的结果。微流变学揭示了富LAPONITE®和贫LAPONITE®区域的不同动力学:贫相表现出液体状行为,而富相表现出凝胶状性质。进一步分析表明,在富相中存在亚微米或纳米级的结构异质性。这些发现为老化和盐浓度如何塑造胶体凝胶的结构和动力学提供了见解。
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来源期刊
Soft Matter
Soft Matter 工程技术-材料科学:综合
CiteScore
6.00
自引率
5.90%
发文量
891
审稿时长
1.9 months
期刊介绍: Soft Matter is an international journal published by the Royal Society of Chemistry using Engineering-Materials Science: A Synthesis as its research focus. It publishes original research articles, review articles, and synthesis articles related to this field, reporting the latest discoveries in the relevant theoretical, practical, and applied disciplines in a timely manner, and aims to promote the rapid exchange of scientific information in this subject area. The journal is an open access journal. The journal is an open access journal and has not been placed on the alert list in the last three years.
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