Investigation of temperature measurements of silicon-containing nonlinear composite varistors

IF 2.3 4区 化学 Q3 CHEMISTRY, PHYSICAL
Shafaq Ahadzade, Tarana Nurubeyli, Gulshan Mammadova, Flora V. Hajiyeva
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引用次数: 0

Abstract

The study investigates the electrical and dielectric properties of polar and non-polar polymer-based composites and Si-based composite varistors across a range of temperatures. Current-voltage characteristics (CVC) were measured, and the real (ε′) and imaginary (ε″) components of the dielectric constant were calculated at different frequencies. The results show that the CVC exhibits non-linearity over the entire measured temperature range, with the breakdown voltage shifting to lower electric fields as temperature increases. The polar polymer-based composites exhibit a current flow approximately five times higher than non-polar composites under the same applied voltage. For polar polymer composites, the dielectric constant (ε) increases monotonically with rising temperature, whereas non-polar polymer composites show a sharp decline in ε with temperature. A decrease in ε″ and loss tangent (tgδ) was observed with increasing temperature. The electrical conductivity (σ) of polar polymer composites decreases monotonically as temperature increases. In contrast, for non-polar polymer composites, σ decreases sharply at low voltages (<50 V) with increasing temperature, while at higher temperatures, σ increases. These findings highlight the contrasting behaviors of polar and non-polar polymer composites under varying thermal and electrical conditions, offering insights into optimizing materials for advanced dielectric and varistor applications.

Graphical Abstract

含硅非线性复合压敏电阻的温度测量研究
该研究调查了极性和非极性聚合物基复合材料和硅基复合压敏电阻在一定温度范围内的电学和介电性能。测量了介电常数的电流-电压特性(CVC),计算了介电常数在不同频率下的实(ε′)和虚(ε″)分量。结果表明,CVC在整个测量温度范围内呈现非线性,击穿电压随温度升高而向较低的电场转移。在相同的施加电压下,极性聚合物基复合材料的电流比非极性复合材料高约5倍。极性聚合物复合材料的介电常数ε随温度的升高而单调增加,而非极性聚合物复合材料的介电常数ε随温度的升高而急剧下降。ε″和损耗切线(tgδ)随温度升高而减小。极性聚合物复合材料的电导率(σ)随温度的升高而单调降低。相反,对于非极性聚合物复合材料,σ在低电压(<50 V)下随着温度的升高而急剧下降,而在较高温度下σ则升高。这些发现突出了极性和非极性聚合物复合材料在不同热和电条件下的不同行为,为优化先进介质和压敏电阻应用的材料提供了见解。图形抽象
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来源期刊
Colloid and Polymer Science
Colloid and Polymer Science 化学-高分子科学
CiteScore
4.60
自引率
4.20%
发文量
111
审稿时长
2.2 months
期刊介绍: Colloid and Polymer Science - a leading international journal of longstanding tradition - is devoted to colloid and polymer science and its interdisciplinary interactions. As such, it responds to a demand which has lost none of its actuality as revealed in the trends of contemporary materials science.
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