Aleksandar Ćirić , Aytaç Gürhan Gökçe , Melis Gökçe , Sanja Kuzman , Zoran Ristić , Bojana Milićević , Deniz Koçyiğit , Miroslav D. Dramićanin
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引用次数: 0
Abstract
This work presents a comprehensive study of high-performance multiparametric luminescent thermometry using Dy3+-doped sodium alumino-borate glass. The glass was synthesized via the melt-quenching method and characterized structurally and optically. Temperature-dependent luminescence properties were investigated, focusing on the luminescence intensity ratio (LIR) of thermally coupled Dy3+ transitions, as well as emission bandwidth and line shift. The Judd-Ofelt model was applied to interpret the thermometric behaviour, showing excellent agreement with experimental results. While the luminescence lifetime remained temperature-invariant, making the material unsuitable for lifetime-based thermometry, steady-state spectral features provided high sensitivity and precision. Multiparametric approaches, including multiple linear regression (MLR) and sensor fusion (SF), were employed to combine different readouts, resulting in enhanced temperature resolution and robustness. The sensor fusion method, in particular, outperformed individual and MLR-based approaches, achieving sub-kelvin temperature resolution at all temperatures. These findings demonstrate that Dy3+-doped sodium alumino-borate glass is a promising candidate for reliable, high-precision luminescent thermometry in demanding environments and the power of multiparametric methods MLR and SF over the individual parameters.
期刊介绍:
The purpose of the Journal of Luminescence is to provide a means of communication between scientists in different disciplines who share a common interest in the electronic excited states of molecular, ionic and covalent systems, whether crystalline, amorphous, or liquid.
We invite original papers and reviews on such subjects as: exciton and polariton dynamics, dynamics of localized excited states, energy and charge transport in ordered and disordered systems, radiative and non-radiative recombination, relaxation processes, vibronic interactions in electronic excited states, photochemistry in condensed systems, excited state resonance, double resonance, spin dynamics, selective excitation spectroscopy, hole burning, coherent processes in excited states, (e.g. coherent optical transients, photon echoes, transient gratings), multiphoton processes, optical bistability, photochromism, and new techniques for the study of excited states. This list is not intended to be exhaustive. Papers in the traditional areas of optical spectroscopy (absorption, MCD, luminescence, Raman scattering) are welcome. Papers on applications (phosphors, scintillators, electro- and cathodo-luminescence, radiography, bioimaging, solar energy, energy conversion, etc.) are also welcome if they present results of scientific, rather than only technological interest. However, papers containing purely theoretical results, not related to phenomena in the excited states, as well as papers using luminescence spectroscopy to perform routine analytical chemistry or biochemistry procedures, are outside the scope of the journal. Some exceptions will be possible at the discretion of the editors.