{"title":"Robust Self-Powered UV Detector Based on a h-ZnTiO3:Ta/p-GaN Epitaxial Heterojunction for High-Temperature Application","authors":"Biao Zhang, , , Xiaochen Ma*, , , Yuankang Wang, , , Hongyan Zhu, , , Caina Luan, , , Jin Ma, , and , Hongdi Xiao*, ","doi":"10.1021/acsaelm.5c00774","DOIUrl":null,"url":null,"abstract":"<p >A self-powered photodetector based on a Ta-doped ZnTiO<sub>3</sub>/p-GaN single-crystal p–n heterojunction with a cross-finger (CF) structure is fabricated. Compared with the flat-plate structure, the CF-type photodetector presented higher photoresponsivity in a wavelength range of 250–350 nm. At zero bias, the UV photodetector with a CF structure exhibits excellent detection performance, including a high responsivity of 0.73 A/W, a good detectivity of 3.98 × 10<sup>12</sup> Jones, and a fast response time of 42.2/10.2 ms. The band composition and working mechanism of the heterojunction detector are elucidated accordingly. Besides, benefiting from the single-crystal structure, the <i>h</i>-ZnTiO<sub>3</sub>:Ta/p-GaN heterojunction self-powered detector maintains robust detection for UV signals at high temperatures. Compared to room temperature, even at 200 °C, the performance of the device only slightly deteriorates, with a responsivity of 0.66 A/W, a detectivity of 2.19 × 10<sup>12</sup> Jones, and a response time of 46.2/11.9 ms. This work provides a good candidate for a stabilized self-powered UV detector applied in high-temperature environments.</p>","PeriodicalId":3,"journal":{"name":"ACS Applied Electronic Materials","volume":"7 18","pages":"8348–8356"},"PeriodicalIF":4.7000,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Electronic Materials","FirstCategoryId":"88","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsaelm.5c00774","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0
Abstract
A self-powered photodetector based on a Ta-doped ZnTiO3/p-GaN single-crystal p–n heterojunction with a cross-finger (CF) structure is fabricated. Compared with the flat-plate structure, the CF-type photodetector presented higher photoresponsivity in a wavelength range of 250–350 nm. At zero bias, the UV photodetector with a CF structure exhibits excellent detection performance, including a high responsivity of 0.73 A/W, a good detectivity of 3.98 × 1012 Jones, and a fast response time of 42.2/10.2 ms. The band composition and working mechanism of the heterojunction detector are elucidated accordingly. Besides, benefiting from the single-crystal structure, the h-ZnTiO3:Ta/p-GaN heterojunction self-powered detector maintains robust detection for UV signals at high temperatures. Compared to room temperature, even at 200 °C, the performance of the device only slightly deteriorates, with a responsivity of 0.66 A/W, a detectivity of 2.19 × 1012 Jones, and a response time of 46.2/11.9 ms. This work provides a good candidate for a stabilized self-powered UV detector applied in high-temperature environments.
期刊介绍:
ACS Applied Electronic Materials is an interdisciplinary journal publishing original research covering all aspects of electronic materials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials science, engineering, optics, physics, and chemistry into important applications of electronic materials. Sample research topics that span the journal's scope are inorganic, organic, ionic and polymeric materials with properties that include conducting, semiconducting, superconducting, insulating, dielectric, magnetic, optoelectronic, piezoelectric, ferroelectric and thermoelectric.
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