{"title":"Self‐Assembled Monolayers for High‐Performance Perovskite Solar Cells","authors":"Shaoyun Jia, Chuantao Gu, Xue Zhou, Yawei Miao, Yong Tian, Shuguang Wen, Jiping Ma, Xichang Bao","doi":"10.1002/adfm.202512747","DOIUrl":null,"url":null,"abstract":"Perovskite solar cells (PSCs) have attracted considerable attention in photovoltaics due to their unique optoelectronic properties and low production costs. Recent advancements have identified self‐assembled monolayers (SAMs) as novel interfacial modification materials that demonstrate exceptional performance as hole transport layers in p‐i‐n structured PSCs. Thanks to the rapid development of SAMs, the power conversion efficiency of PSCs has exceeded 27%. However, the progress of SAM materials has encountered bottlenecks, facing challenges such as molecular aggregation, poor wettability, and long‐term stability. Therefore, comprehensive review and analysis of SAM is crucial for developing SAM materials. This paper reviews the research progress of SAMs in recent years, systematically analyzes the structural design and functional roles of SAMs in PSCs, and provides an outlook on the design of novel SAMs and their commercialization. It is believed that this review will help the development of functional and new SAMs for practical application of PSCs.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"38 1","pages":""},"PeriodicalIF":19.0000,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Functional Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adfm.202512747","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Perovskite solar cells (PSCs) have attracted considerable attention in photovoltaics due to their unique optoelectronic properties and low production costs. Recent advancements have identified self‐assembled monolayers (SAMs) as novel interfacial modification materials that demonstrate exceptional performance as hole transport layers in p‐i‐n structured PSCs. Thanks to the rapid development of SAMs, the power conversion efficiency of PSCs has exceeded 27%. However, the progress of SAM materials has encountered bottlenecks, facing challenges such as molecular aggregation, poor wettability, and long‐term stability. Therefore, comprehensive review and analysis of SAM is crucial for developing SAM materials. This paper reviews the research progress of SAMs in recent years, systematically analyzes the structural design and functional roles of SAMs in PSCs, and provides an outlook on the design of novel SAMs and their commercialization. It is believed that this review will help the development of functional and new SAMs for practical application of PSCs.
钙钛矿太阳能电池(PSCs)由于其独特的光电性能和低廉的生产成本在光伏领域引起了广泛的关注。最近的进展表明,自组装单层(sam)是一种新型的界面改性材料,在p - i - n结构psc中表现出优异的空穴传输层性能。由于地对空导弹的快速发展,PSCs的功率转换效率已超过27%。然而,SAM材料的进展遇到了瓶颈,面临着诸如分子聚集、润湿性差和长期稳定性等挑战。因此,全面回顾和分析地空导弹是开发地空导弹材料的关键。本文综述了近年来地对空导弹的研究进展,系统分析了地对空导弹的结构设计和在psc中的功能作用,并对新型地对空导弹的设计和商业化进行了展望。相信本文的综述将有助于开发功能性和新型的自适应自适应材料,为其实际应用提供参考。
期刊介绍:
Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week.
Advanced Functional Materials is known for its rapid and fair peer review, quality content, and high impact, making it the first choice of the international materials science community.