Advancements in nitrated nanocellulose: from structural insights to energetic applications

IF 4.8 2区 工程技术 Q1 MATERIALS SCIENCE, PAPER & WOOD
Nurul Farhana Ahmad Aljafree, Mohd Nor Faiz Norrrahim, Alinda Samsuri, Wan Md Zin Wan Yunus
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Abstract

This review explores the structural and chemical properties of nitrated nanocellulose, highlighting its transformative potential in energetic applications. Derived from cellulose nanocrystals (CNCs), cellulose nanofibrils (CNFs), and bacterial nanocellulose (BNC), nitrated nanocellulose combines the inherent advantages of nanocellulose such as mechanical strength, large surface area, and biodegradability with enhanced energetic properties achieved through nitration. The impact of nitrated nanocellulose in energetic materials extends to its ability to contribute to greener, more sustainable energy solutions by reducing reliance on traditional petrochemical-based components. The review delves into various nitration techniques, including mixed acid and catalytic systems, which convert nanocellulose into nitrocellulose with tailored properties. These nitrated forms exhibit improved mechanical stability, reduced sensitivity to external stimuli, and enhanced safety profiles, making them promising candidates for applications in explosives, propellants, and energy storage. The review concludes by outlining future research directions, emphasizing the need for further exploration of synthesis methods, and integration into advanced energetic systems to fully unlock the transformative potential of nitrated nanocellulose in materials science and energetic technologies.

硝化纳米纤维素的进展:从结构见解到能量应用
本文综述了硝化纳米纤维素的结构和化学性质,强调了其在能源应用中的转化潜力。硝化纳米纤维素来源于纤维素纳米晶体(CNCs)、纤维素纳米原纤维(CNFs)和细菌纳米纤维素(BNC),它结合了纳米纤维素的固有优点,如机械强度、大表面积和生物降解性,并通过硝化获得了增强的能量特性。硝化纳米纤维素在高能材料中的影响延伸到它通过减少对传统石化组件的依赖,为更环保、更可持续的能源解决方案做出贡献的能力。该综述深入探讨了各种硝化技术,包括混合酸和催化系统,将纳米纤维素转化为具有特定性能的硝化纤维素。这些硝化形式表现出更好的机械稳定性,降低了对外部刺激的敏感性,并增强了安全性,使其成为爆炸物,推进剂和储能应用的有希望的候选者。总结了未来的研究方向,强调需要进一步探索合成方法,并与先进的能量系统相结合,以充分释放硝化纳米纤维素在材料科学和能源技术方面的变革潜力。
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来源期刊
Cellulose
Cellulose 工程技术-材料科学:纺织
CiteScore
10.10
自引率
10.50%
发文量
580
审稿时长
3-8 weeks
期刊介绍: Cellulose is an international journal devoted to the dissemination of research and scientific and technological progress in the field of cellulose and related naturally occurring polymers. The journal is concerned with the pure and applied science of cellulose and related materials, and also with the development of relevant new technologies. This includes the chemistry, biochemistry, physics and materials science of cellulose and its sources, including wood and other biomass resources, and their derivatives. Coverage extends to the conversion of these polymers and resources into manufactured goods, such as pulp, paper, textiles, and manufactured as well natural fibers, and to the chemistry of materials used in their processing. Cellulose publishes review articles, research papers, and technical notes.
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