Yong Li , Hao Wang , Chenyang Wang , Liye Wang , Chenglin Liao , Lifang Wang
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引用次数: 0
Abstract
The growing use of lithium-ion batteries in electric transportation and grid-scale storage systems has intensified the need for accurate and highly generalizable state-of-health (SOH) estimation. Conventional approaches often suffer from reduced accuracy under dynamically uncertain state-of-charge (SOC) operating ranges and heterogeneous aging stresses. This study presents a unified SOH estimation framework that integrates physics-informed modeling, subspace identification, and Transformer-based learning. A reduced-order model is derived from simplified electrochemical dynamics, providing an interpretable and computationally efficient representation of battery behavior. Subspace identification across a wide SOC and SOH range yields degradation-sensitive features, which the Transformer uses to capture long-range aging dynamics via multi-head self-attention. Experiments on LiFePO4 cells under joint-cell training show consistently accurate SOH estimation, with a maximum error of 1.39 %, demonstrating the framework’s effectiveness in decoupling SOC and SOH effects. In cross-cell validation, where training and validation are performed on different cells, the model maintains a maximum error of 2.06 %, confirming strong generalization to unseen aging trajectories. Comparative experiments on LiFePO4 and public LiCoO2 datasets confirm the framework’s cross-chemistry applicability. By extracting low-dimensional, physically interpretable features via subspace identification, the framework significantly reduces training cost while maintaining high SOH estimation accuracy, outperforming conventional data-driven models lacking physical guidance.
期刊介绍:
The Journal of Energy Chemistry, the official publication of Science Press and the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, serves as a platform for reporting creative research and innovative applications in energy chemistry. It mainly reports on creative researches and innovative applications of chemical conversions of fossil energy, carbon dioxide, electrochemical energy and hydrogen energy, as well as the conversions of biomass and solar energy related with chemical issues to promote academic exchanges in the field of energy chemistry and to accelerate the exploration, research and development of energy science and technologies.
This journal focuses on original research papers covering various topics within energy chemistry worldwide, including:
Optimized utilization of fossil energy
Hydrogen energy
Conversion and storage of electrochemical energy
Capture, storage, and chemical conversion of carbon dioxide
Materials and nanotechnologies for energy conversion and storage
Chemistry in biomass conversion
Chemistry in the utilization of solar energy