High-strength self-compacting alkali-activated concrete produced with fly ash and steel slag: rheological behavior and mixing rheology comparisons with a Portland cement concrete

Lucas B.R. Araújo , Madson L. de Souza , Abcael R.S. Melo , Heloina N. Costa , Lucas F.A.L. Babadopulos , Antonio E.B. Cabral , Rafael G. Pileggi
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Abstract

The construction industry has recently seen a growing demand for sustainable materials. Alkali-activated binders (AAB) have emerged as a viable alternative to Portland cement-based materials. This study investigates the influences of the composition and mixing methods on the rheological and mechanical properties of an alkali-activated concrete (AAC) based on fly ash (FA) and steel slag (SS), compared to a reference Portland cement concrete (PCC) with equivalent volume fractions of aggregate and paste. Two mixing methods were examined: a free fall mixer and a planetary mixer that also functions as a rheometer. In the fresh state, the performance of concretes was assessed, focusing on rheological parameters such as mixing energy, maximum torque, and equivalent apparent viscosity indicator. In the hardened state, compressive strength tests were conducted. Pseudoplastic rheological model effectively described AAC behavior, while the Bingham model better characterized PCC. AAC demonstrated high passing ability and extended flow time, with flow behavior significantly influenced by the mixing process. Rheological analysis revealed that AAC required five times more mixing energy and exhibited greater equivalent apparent viscosity indicator compared to PCC. Additionally, AAC achieved higher compressive strength than PCC, which presented values from 34 to 43 MPa (PCC) depending on curing conditions. Thermal curing increased compressive strength by nearly 60 % at 28 days for AAC, from 48.6 MPa to 76.8 MPa. Furthermore, the mixing procedure influenced the fresh and hardened properties of both AAC and PCC, though PCC exhibited only minor variations. Mixing methods with higher energy input led to improved compressive strength.
粉煤灰和钢渣生产的高强度自密实碱活化混凝土:流变特性和与波特兰水泥混凝土的混合流变比较
最近,建筑行业对可持续材料的需求不断增长。碱活化粘合剂(AAB)已成为波特兰水泥基材料的可行替代品。本研究探讨了组成和搅拌方法对粉煤灰(FA)和钢渣(SS)碱活化混凝土(AAC)流变学和力学性能的影响,并与具有等体积分数骨料和膏体的参考波特兰水泥混凝土(PCC)进行了比较。研究了两种混合方法:一种是自由落体混合器,另一种是具有流变仪功能的行星混合器。在新鲜状态下,评估混凝土的性能,重点是流变参数,如搅拌能,最大扭矩和等效表观粘度指标。在硬化状态下进行抗压强度试验。假塑性流变模型能较好地描述AAC行为,Bingham模型能较好地表征PCC。AAC具有较高的通过能力和较长的流动时间,其流动特性受混合过程的影响较大。流变学分析表明,与PCC相比,AAC所需的混合能是PCC的5倍,其等效表观粘度指标也更高。此外,AAC的抗压强度高于PCC,根据养护条件的不同,其值为34 ~ 43 MPa (PCC)。热固化28天后,AAC的抗压强度提高了近60%,从48.6 MPa提高到76.8 MPa。此外,混合过程对AAC和PCC的新鲜和硬化性能都有影响,尽管PCC的变化很小。采用高能量输入的混合方法可提高材料的抗压强度。
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