Strength–conductivity synergy in Cu–Cr alloy induced by rotary swaging: Microstructure reconstruction and interface optimization

IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Song Liu , Shaolin Li , Kexing Song , Xiaowen Peng , Xiuhua Guo , Zhenhan Zhou , Shuaibin Li , Fuxiao Chen
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Abstract

CuCr alloys, owing to their excellent electrical conductivity and high strengthening potential, have broad applications in high-performance electrical engineering materials. In this study, a synergistic microstructural regulation strategy combining room-temperature rotary swaging (RS) with subsequent aging was proposed to construct a “load-bearing-conduction compatible” architecture, enabling simultaneous enhancement of strength and electrical conductivity in a CuCr alloy (0.5 wt% Cr). The RS process induced pronounced axial grain elongation (aspect ratio ≈ 11) and promoted the enrichment and ordered arrangement of dislocations along microband boundaries, thereby forming a localized substructural network that integrates high-density strengthening with low-scattering conduction. Concurrently, RS accelerated Cr precipitation and facilitated a transition of precipitate-matrix interfaces from coherent to incoherent, significantly mitigating interfacial scattering. In addition, partial discontinuous dynamic recrystallization generated low-distortion grains, further optimizing electron migration pathways. As a synergistic outcome of these mechanisms, the yield strength increased from 404 MPa to 494 MPa, while the electrical conductivity improved from 71.3 % IACS to 82.2 % IACS. This dislocation-interface synergy overcomes the traditional trade-off between strength and conductivity, and, owing to the efficiency and scalability of the RS-aging process, offers a viable route for high-performance microstructural design and large-scale production of Cu-based alloys.
Cu-Cr合金的强度-电导率协同效应:微观组织重建与界面优化
Cu-Cr合金具有优良的导电性和较高的强化潜力,在高性能电气工程材料中有着广泛的应用。在本研究中,提出了一种将室温旋转锻压(RS)与后续时效相结合的协同显微组织调节策略,以构建“承载-传导兼容”结构,从而同时增强Cu-Cr合金(0.5 wt% Cr)的强度和导电性。RS过程诱导了显著的轴向晶粒伸长(长径比≈11),促进了微带边界位错的富集和有序排列,从而形成了高密度强化和低散射传导相结合的局域子结构网络。同时,RS加速了Cr的析出,促进了沉淀-基体界面从相干到非相干的转变,显著减轻了界面散射。此外,局部不连续动态再结晶产生了低畸变晶粒,进一步优化了电子迁移途径。作为这些机制的协同结果,屈服强度从404 MPa提高到494 MPa,电导率从71.3%提高到82.2%。这种位错-界面协同作用克服了传统强度和导电性之间的权衡,并且由于rs时效工艺的效率和可扩展性,为高性能微结构设计和大规模生产cu基合金提供了可行的途径。
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来源期刊
Materials Science and Engineering: A
Materials Science and Engineering: A 工程技术-材料科学:综合
CiteScore
11.50
自引率
15.60%
发文量
1811
审稿时长
31 days
期刊介绍: Materials Science and Engineering A provides an international medium for the publication of theoretical and experimental studies related to the load-bearing capacity of materials as influenced by their basic properties, processing history, microstructure and operating environment. Appropriate submissions to Materials Science and Engineering A should include scientific and/or engineering factors which affect the microstructure - strength relationships of materials and report the changes to mechanical behavior.
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