Effects of transverse magnetic field on the directional solidification structure and segregation behavior of Co-Al-W-based superalloy

IF 4.6 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Jiang Zhang , Chao Zhang , Zhi-Bin Yang , Jian-Bo Yu , Jie Huang , Jun-Feng Li
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Abstract

Directional solidification experiments were conducted on the Co-Al-W-based superalloy under an external magnetic field. The results showed that depression occurred on the right side of the solid-liquid interface at a pulling rate of 5 μm/s, and the Al solute segregated to this side. Spotty segregation also occurred on the sample's right side, and applying an external magnetic field reduced the primary dendrite arm spacing. After the pulling rate reached 50 μm/s, the magnetic field barely had any influence on the solid-liquid interface of the alloy. The primary dendrite arm spacing did not decrease further as the magnetic flux density increased beyond a certain point. This observation could be explained by the shortened action of the thermoelectromagnetic flow in the interdendritic space at an increasing pulling rate under a transverse magnetic field. At a pulling rate of 5 μm/s, the solid-liquid interface and the flow state of the interdendritic melt were altered during the solidification process with an external magnetic field than without one. Moreover, the melt flow had a significant impact on the alloy microstructure, as a result of thermoelectromagnetic convection along the solid-liquid interface induced by the magnetic field. A magnetic field dramatically intensified thermoelectromagnetic convection, facilitating interdendritic melt flow and continuously reducing the primary dendrite arm spacing.
横向磁场对co - al - w基高温合金定向凝固组织及偏析行为的影响
对co - al - w基高温合金进行了外磁场定向凝固实验。结果表明:当拉伸速率为5 μm/s时,固液界面右侧出现凹陷,Al溶质向右侧偏析;在样品的右侧也出现了点状偏析,施加外部磁场减少了初级枝晶臂间距。当拉伸速率达到50 μm/s后,磁场对合金的固液界面几乎没有影响。当磁通密度超过一定程度后,初生枝晶臂间距不再随着磁通密度的增大而进一步减小。这一现象可以解释为在横向磁场作用下,热电磁流在枝晶间空间的作用时间缩短,拉速增加。在拉拔速率为5 μm/s时,外加磁场比无外加磁场更能改变枝晶间熔体的固液界面和流动状态。此外,熔体流动对合金的微观组织有显著影响,这是由于磁场引起的沿固液界面的热电磁对流。磁场显著增强了热电磁对流,促进了枝晶间的熔体流动,并不断减小了初生枝晶臂间距。
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来源期刊
CiteScore
7.00
自引率
13.90%
发文量
236
审稿时长
35 days
期刊介绍: The International Journal of Refractory Metals and Hard Materials (IJRMHM) publishes original research articles concerned with all aspects of refractory metals and hard materials. Refractory metals are defined as metals with melting points higher than 1800 °C. These are tungsten, molybdenum, chromium, tantalum, niobium, hafnium, and rhenium, as well as many compounds and alloys based thereupon. Hard materials that are included in the scope of this journal are defined as materials with hardness values higher than 1000 kg/mm2, primarily intended for applications as manufacturing tools or wear resistant components in mechanical systems. Thus they encompass carbides, nitrides and borides of metals, and related compounds. A special focus of this journal is put on the family of hardmetals, which is also known as cemented tungsten carbide, and cermets which are based on titanium carbide and carbonitrides with or without a metal binder. Ceramics and superhard materials including diamond and cubic boron nitride may also be accepted provided the subject material is presented as hard materials as defined above.
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