Impact Wear Evolution Mechanism of Fe2Ni2CrV0.5Nb0.8 Eutectic High-Entropy Alloy Coating under Dynamic Cyclic Impacts

IF 3.3 3区 材料科学 Q2 MATERIALS SCIENCE, COATINGS & FILMS
Yingying Li, Hao Liu, Wenqin Wang, Sining Pan, Peijian Chen, Xiuli He, Gang Yu
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Abstract

The dynamic impact test of eutectic high-entropy alloy (EHEA) coating composed of alternating arrangement of soft and hard phases is employed to investigate the damage accumulation principles under impact cycles combined with microstructure characteristic. The Fe2Ni2CrV0.5Nb0.8 EHEA coating presents a typical hypoeutectic alloys structure with the lamellar eutectic colonies of Laves and FCC phase uniformly dispersed within the primary FCC solid solution matrix. The Laves phase, serving as the primary load-bearing constituent, provides exceptional deformation resistance, while the FCC phase accommodates plastic strain to mitigate stress concentration and suppress crack initiation. The coating undergoes plastic deformation during the initial stage (10–1000 cycles), and the impact wear volume increases slowly. The impact energy dissipation under impact loading is predominantly attributed to elastic–plastic deformation. The slight edge damage stage exceeding 5000 cycles is characterized by oxidative wear. The tangential shear force at the edge position induce material spalling and accelerating impact wear volume growth, progressively elevating energy loss via wear. As the impact cycles approaches 15000, the material exhausts its capacity for further plastic deformation, shifting energy dissipation predominantly to wear-driven mechanisms. The high residual stresses formed on the impact crater surface initiate microcracks, promoting oxide layer exfoliation. Fatigue wear governs the failure mechanism, accompanied by a sharp rise in wear rate due to cyclic stress-induced crack propagation.

动态循环冲击下Fe2Ni2CrV0.5Nb0.8共晶高熵合金涂层冲击磨损演化机理
采用软硬相间排列的共晶高熵合金(EHEA)涂层的动态冲击试验,结合微观组织特征,研究了冲击循环下的损伤积累原理。Fe2Ni2CrV0.5Nb0.8 EHEA涂层呈现出典型的亚共晶合金组织,Laves和FCC相的片层共晶菌落均匀分布在初生FCC固溶体基体中。Laves相作为主要的承重成分,提供了出色的抗变形能力,而FCC相则适应塑性应变,以减轻应力集中并抑制裂纹萌生。涂层在初始阶段(10 ~ 1000次循环)发生塑性变形,冲击磨损体积增长缓慢。冲击载荷作用下的冲击能量耗散主要来源于弹塑性变形。超过5000次循环的轻微边缘损伤阶段以氧化磨损为特征。边缘位置的切向剪切力导致材料剥落,加速冲击磨损体积的增长,逐渐增加磨损带来的能量损失。当冲击循环次数接近15000次时,材料将耗尽其进一步塑性变形的能力,将能量耗散主要转移到磨损驱动机制。撞击坑表面形成的高残余应力引发微裂纹,促进氧化层剥落。疲劳磨损主导了失效机制,同时由于循环应力引起的裂纹扩展,磨损率急剧上升。
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来源期刊
Journal of Thermal Spray Technology
Journal of Thermal Spray Technology 工程技术-材料科学:膜
CiteScore
5.20
自引率
25.80%
发文量
198
审稿时长
2.6 months
期刊介绍: From the scientific to the practical, stay on top of advances in this fast-growing coating technology with ASM International''s Journal of Thermal Spray Technology. Critically reviewed scientific papers and engineering articles combine the best of new research with the latest applications and problem solving. A service of the ASM Thermal Spray Society (TSS), the Journal of Thermal Spray Technology covers all fundamental and practical aspects of thermal spray science, including processes, feedstock manufacture, and testing and characterization. The journal contains worldwide coverage of the latest research, products, equipment and process developments, and includes technical note case studies from real-time applications and in-depth topical reviews.
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