Multi-Condition Classification of Oil Spill in Ice Areas Based on Laser-Induced Fluorescence.

IF 3.1 4区 化学 Q2 BIOCHEMICAL RESEARCH METHODS
Chenyu Zhao, Ying Li, Qintuan Xu, Yong Wang, Ming Xie, Xiangxiang Ji
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引用次数: 0

Abstract

Oil spill detection in ice-covered marine environments poses considerable challenges due to fluorescence signal interference from ice, heterogeneous surface properties, and environmental complexity. To address the lack of high-precision oil classification methods under such conditions, this study introduces a fluorescence-based multi-condition classification framework that integrates laser-induced fluorescence (LIF) spectroscopy with a machine learning model optimized by the Golden Sine Algorithm (Gold-SA). LIF spectra were collected for six oil types under four simulated ice coverage and oil volume scenarios, resulting in 24 distinct classification categories. Fluorescence signals underwent denoising using Savitzky-Golay (SG) filtering to improve signal stability and spectral reliability. The resulting Gold-SA-CatBoost model achieved 99.62% accuracy under laboratory conditions within the dataset and 100% accuracy in single-task oil-type identification, surpassing baseline models by a substantial margin. This work demonstrates the efficacy of integrating LIF with advanced optimization-based machine learning for robust oil spill detection under complex icy conditions. The proposed approach provides a viable fluorescence-based strategy for environmental monitoring in cold and polar marine regions.

基于激光诱导荧光的冰区溢油多条件分类
由于冰的荧光信号干扰、非均匀的表面性质和环境的复杂性,在冰覆盖的海洋环境中进行溢油检测面临着相当大的挑战。为了解决在这种条件下缺乏高精度油分类方法的问题,本研究引入了一种基于荧光的多条件分类框架,该框架将激光诱导荧光(LIF)光谱与由金正弦算法(Gold-SA)优化的机器学习模型相结合。在4种模拟冰覆盖和含油量情景下,收集了6种油类的LIF光谱,得到了24种不同的分类类别。采用Savitzky-Golay (SG)滤波对荧光信号进行去噪,提高信号稳定性和光谱可靠性。由此产生的Gold-SA-CatBoost模型在数据集的实验室条件下达到99.62%的准确率,在单任务油类型识别中达到100%的准确率,大大超过了基线模型。这项工作证明了将LIF与先进的基于优化的机器学习相结合,在复杂的冰况下进行稳健的溢油检测的有效性。提出的方法为寒冷和极地海洋地区的环境监测提供了一种可行的基于荧光的策略。
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来源期刊
Journal of Fluorescence
Journal of Fluorescence 化学-分析化学
CiteScore
4.60
自引率
7.40%
发文量
203
审稿时长
5.4 months
期刊介绍: Journal of Fluorescence is an international forum for the publication of peer-reviewed original articles that advance the practice of this established spectroscopic technique. Topics covered include advances in theory/and or data analysis, studies of the photophysics of aromatic molecules, solvent, and environmental effects, development of stationary or time-resolved measurements, advances in fluorescence microscopy, imaging, photobleaching/recovery measurements, and/or phosphorescence for studies of cell biology, chemical biology and the advanced uses of fluorescence in flow cytometry/analysis, immunology, high throughput screening/drug discovery, DNA sequencing/arrays, genomics and proteomics. Typical applications might include studies of macromolecular dynamics and conformation, intracellular chemistry, and gene expression. The journal also publishes papers that describe the synthesis and characterization of new fluorophores, particularly those displaying unique sensitivities and/or optical properties. In addition to original articles, the Journal also publishes reviews, rapid communications, short communications, letters to the editor, topical news articles, and technical and design notes.
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