Ru-catalyzed deoxydehydration (DODH) with hydrazine

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-09-12 DOI:10.1039/d5cc04813c

Siyi Luo , Chen-Chen Li , Zihang Qiu , Ruofei Cheng , Chao-Jun Li

引用次数: 0

Abstract

A novel method for the deoxydehydration (DODH) of diols to alkenes has been developed by using hydrazine as a reductant via HOME (hydrazone as an organometallic equivalent) chemistry catalyzed by Ru-PNP complexes. This process avoids harsh reaction conditions, minimizes waste, and can be applied to a variety of diol compounds.

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钌催化肼脱氧脱水（DODH）

以肼为还原剂，在Ru-PNP配合物的催化下，通过HOME（腙作为有机金属当量）化学反应，建立了二醇脱氧脱水制烯烃的新方法。该工艺避免了苛刻的反应条件，最大限度地减少了浪费，并可应用于各种二醇化合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.