Thermodynamic, acoustic and spectroscopic investigation of choline salicylate ternary mixtures with sodium salts over temperature range 288.15–318.15 K
{"title":"Thermodynamic, acoustic and spectroscopic investigation of choline salicylate ternary mixtures with sodium salts over temperature range 288.15–318.15 K","authors":"Mashahid Hussain Choudhary , Nabaparna Chakraborty , Kailash Chandra Juglan","doi":"10.1016/j.chemphys.2025.112918","DOIUrl":null,"url":null,"abstract":"<div><div>This study explores molecular interactions in ternary mixtures of (choline salicylate + water + and trisodium citrate /sodium nitrate) by measuring density and sound velocity at four temperatures and varying concentrations. Thermoacoustic parameters were calculated to understand solute–solvent interactions. Relative association and relaxation strength were analyzed to assess molecular aggregation and structural rearrangements. FTIR analysis of binary and ternary mixtures of choline salicylate with salts further revealed bonding characteristics. The findings offer insights into intermolecular forces and solvation dynamics, aiding the development of efficient pharmaceutical processes and promoting environmentally sustainable practices. The study contributes to scientific knowledge and supports key Sustainable Development Goals (SDGs).</div></div>","PeriodicalId":272,"journal":{"name":"Chemical Physics","volume":"601 ","pages":"Article 112918"},"PeriodicalIF":2.4000,"publicationDate":"2025-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Physics","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0301010425003192","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
This study explores molecular interactions in ternary mixtures of (choline salicylate + water + and trisodium citrate /sodium nitrate) by measuring density and sound velocity at four temperatures and varying concentrations. Thermoacoustic parameters were calculated to understand solute–solvent interactions. Relative association and relaxation strength were analyzed to assess molecular aggregation and structural rearrangements. FTIR analysis of binary and ternary mixtures of choline salicylate with salts further revealed bonding characteristics. The findings offer insights into intermolecular forces and solvation dynamics, aiding the development of efficient pharmaceutical processes and promoting environmentally sustainable practices. The study contributes to scientific knowledge and supports key Sustainable Development Goals (SDGs).
期刊介绍:
Chemical Physics publishes experimental and theoretical papers on all aspects of chemical physics. In this journal, experiments are related to theory, and in turn theoretical papers are related to present or future experiments. Subjects covered include: spectroscopy and molecular structure, interacting systems, relaxation phenomena, biological systems, materials, fundamental problems in molecular reactivity, molecular quantum theory and statistical mechanics. Computational chemistry studies of routine character are not appropriate for this journal.