{"title":"Biomimetic Strawberry-Structured Micro/Nano Fibers as Positive Friction Layers for High-Performance Triboelectric Nanogenerators","authors":"Chenglei Ru, , , Jing Yin, , and , Lan Xu*, ","doi":"10.1021/acs.biomac.5c01403","DOIUrl":null,"url":null,"abstract":"<p >Electrospun triboelectric nanogenerators (TENGs) are favored in flexible, wearable devices. In this article, the positive friction layers of TENGs with biomimetic strawberry structures were efficiently prepared using free-surface electrospinning technology. The dielectric constant of multistrawberry-structured (MSS) micro/nano fibers with the highest specific surface area was increased by about 1.5 times, significantly enhancing the charge-trapping ability of positive friction layers. Subsequently, the effects of fiber microstructure, contact area, membrane thickness, external force, air gap, and frequency on the output properties of MSS-TENG were explored. The optimal device performed well at 25 N and 3 Hz, with an open-circuit voltage of 301.93 V, a short-circuit current of 7.34 μA, a transfer charge of 103.89 nC, and a power density of 0.617 W/m<sup>2</sup>, lighting up 300 light-emitting diodes and driving portable electronic devices to operate normally. Moreover, MSS-TENG could maintain stable output after nearly 40 min of cycling.</p>","PeriodicalId":30,"journal":{"name":"Biomacromolecules","volume":"26 10","pages":"7097–7107"},"PeriodicalIF":5.4000,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Biomacromolecules","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.biomac.5c01403","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"BIOCHEMISTRY & MOLECULAR BIOLOGY","Score":null,"Total":0}
引用次数: 0
Abstract
Electrospun triboelectric nanogenerators (TENGs) are favored in flexible, wearable devices. In this article, the positive friction layers of TENGs with biomimetic strawberry structures were efficiently prepared using free-surface electrospinning technology. The dielectric constant of multistrawberry-structured (MSS) micro/nano fibers with the highest specific surface area was increased by about 1.5 times, significantly enhancing the charge-trapping ability of positive friction layers. Subsequently, the effects of fiber microstructure, contact area, membrane thickness, external force, air gap, and frequency on the output properties of MSS-TENG were explored. The optimal device performed well at 25 N and 3 Hz, with an open-circuit voltage of 301.93 V, a short-circuit current of 7.34 μA, a transfer charge of 103.89 nC, and a power density of 0.617 W/m2, lighting up 300 light-emitting diodes and driving portable electronic devices to operate normally. Moreover, MSS-TENG could maintain stable output after nearly 40 min of cycling.
期刊介绍:
Biomacromolecules is a leading forum for the dissemination of cutting-edge research at the interface of polymer science and biology. Submissions to Biomacromolecules should contain strong elements of innovation in terms of macromolecular design, synthesis and characterization, or in the application of polymer materials to biology and medicine.
Topics covered by Biomacromolecules include, but are not exclusively limited to: sustainable polymers, polymers based on natural and renewable resources, degradable polymers, polymer conjugates, polymeric drugs, polymers in biocatalysis, biomacromolecular assembly, biomimetic polymers, polymer-biomineral hybrids, biomimetic-polymer processing, polymer recycling, bioactive polymer surfaces, original polymer design for biomedical applications such as immunotherapy, drug delivery, gene delivery, antimicrobial applications, diagnostic imaging and biosensing, polymers in tissue engineering and regenerative medicine, polymeric scaffolds and hydrogels for cell culture and delivery.