Phase Behavior, Dye Extraction, and Potential for Pretreating Textile Effluents in Aqueous Two-Phase Systems of Nonionic Surfactants (Tween 20 or Tween 80) and Organic Salts (Sodium Citrate or Sodium Tartrate)

IF 2.1 3区 工程技术 Q3 CHEMISTRY, MULTIDISCIPLINARY
Renata Aparecida Fideles, Lohayne Ligya Barbosa Silva Nascimento, Matheus Torres Duarte Figueiredo, Amanda Luise Pereira Murta, Melany Alejandra Ruiz Lopez, Aparecida Barbosa Mageste and Gabriel Max Dias Ferreira*, 
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引用次数: 0

Abstract

Aqueous two-phase systems (ATPSs) based on nonionic surfactant (Tween 20 or Tween 80) and organic salt (sodium citrate or sodium tartrate) are proposed as alternatives for dye extraction and pretreatment of textile effluents. The newly studied ATPSs exhibited an upper phase rich in surfactant and a lower phase rich in salt. An increase in temperature expanded the biphasic region, altered the phase compositions, and increased the tie-line length. Systems containing citrate exhibited larger biphasic regions due to its higher hydration capacity, while Tween 80 promoted greater phase separation than Tween 20, attributed to its higher hydrophobicity. Partitioning studies with rhodamine B and methyl orange showed preferential dye transference to the surfactant-rich phase, with extraction percentages above 98.7% and 99.2%, respectively. When applied to a textile effluent, the formation of ATPSs using the effluent as solvent led to an expanded immiscibility region in tartrate-based systems. Additionally, color removal efficiency remained above 91.52%, regardless of overall system composition or phase mass ratio, demonstrating the practical feasibility of using these ATPSs for the pretreatment of textile effluents. To the best of our knowledge, this is the first study to evaluate the effect of textile effluent composition on both the formation and dye extraction performance of Tween-based ATPSs.

在非离子表面活性剂(吐温20或吐温80)和有机盐(柠檬酸钠或酒石酸钠)的水两相系统中,相行为、染料萃取和预处理纺织废水的潜力
提出了基于非离子表面活性剂(Tween 20或Tween 80)和有机盐(柠檬酸钠或酒石酸钠)的双水相体系(atps)作为染料提取和纺织废水预处理的替代方案。新研究的atps表现为富表面活性剂的上相和富盐的下相。温度的升高扩大了双相区,改变了相组成,增加了系线长度。含有柠檬酸盐的体系由于其较高的水合能力而表现出更大的双相区,而Tween 80由于其较高的疏水性而比Tween 20促进了更大的相分离。罗丹明B和甲基橙的分配研究表明,染料优先转移到富含表面活性剂的相,萃取率分别高于98.7%和99.2%。当应用于纺织废水时,使用废水作为溶剂形成的atps导致酒石酸盐基系统中的不混溶区域扩大。此外,无论系统整体组成或相质量比如何,去色效率均保持在91.52%以上,表明将这些atps用于纺织废水预处理的实际可行性。据我们所知,这是第一个评估纺织废水成分对tween基atps形成和染料提取性能影响的研究。
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来源期刊
Journal of Chemical & Engineering Data
Journal of Chemical & Engineering Data 工程技术-工程:化工
CiteScore
5.20
自引率
19.20%
发文量
324
审稿时长
2.2 months
期刊介绍: The Journal of Chemical & Engineering Data is a monthly journal devoted to the publication of data obtained from both experiment and computation, which are viewed as complementary. It is the only American Chemical Society journal primarily concerned with articles containing data on the phase behavior and the physical, thermodynamic, and transport properties of well-defined materials, including complex mixtures of known compositions. While environmental and biological samples are of interest, their compositions must be known and reproducible. As a result, adsorption on natural product materials does not generally fit within the scope of Journal of Chemical & Engineering Data.
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