Comprehensive Physicochemical Investigation of the Water-Soluble Adduct of C60 with l-Methionine (C60(C5H11NO2S)3): Important Data for Further Applications
Konstantin N. Semenov*, Ali Mlhem, Alexander V. Akentiev, Dmitry A. Nerukh, Natalia V. Petukhova, Ilnaz T. Rakipov, Kirill V. Timoshchuk, Gleb O. Iurev, Andrey V. Petrov, Igor V. Murin, Nikolay A. Charykov, Olga S. Vezo, Anastasia V. Penkova, Dilafruz K. Kholmurodova, Jasur A. Rizaev, Aziz S. Kubaev and Vladimir V. Sharoyko*,
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引用次数: 0
Abstract
This work is devoted to the study of the physicochemical properties of the water-soluble adduct fullerene C60-l-methionine. The adduct was characterized using 13C solid-state NMR spectroscopy, IR spectroscopy, elemental analysis, UV/vis spectroscopy, and HPLC. The measured physicochemical properties included density, viscosity, refraction, electrical conductivity, speed of sound, surface properties of aqueous solutions, nanoparticle size distribution in water, the molecular dynamics simulation of the association of C60-Met molecules in water and isotonic saline (0.15 M NaCl solutions), the study of solubility in binary C60-Met–H2O and ternary C60-Met–NaCl–H2O systems, as well as their distribution in the n-octan-1-ol–water system.
期刊介绍:
The Journal of Chemical & Engineering Data is a monthly journal devoted to the publication of data obtained from both experiment and computation, which are viewed as complementary. It is the only American Chemical Society journal primarily concerned with articles containing data on the phase behavior and the physical, thermodynamic, and transport properties of well-defined materials, including complex mixtures of known compositions. While environmental and biological samples are of interest, their compositions must be known and reproducible. As a result, adsorption on natural product materials does not generally fit within the scope of Journal of Chemical & Engineering Data.