{"title":"Pico-second pulse electron irradiation damage studies in crystalline silicon solar cells","authors":"Aram Sahakyan , Vachagan Harutyunyan , Norik Grigoryan , Arpine Martirosyan , Norair Martirosyan , Ashot Vardanyan , Christopher Rhodes , Eduard Aleksanyan","doi":"10.1016/j.solmat.2025.113956","DOIUrl":null,"url":null,"abstract":"<div><div>This study investigates the effects of picosecond electron irradiation on the performance parameters of commercial crystalline silicon solar cells fabricated using Passivated Emitter and Rear Contact (PERC) solar technology. The irradiation was performed using electrons with energies up to 3.6 MeV, a pulse current density of j<sub>pulse</sub> = 200 A/cm<sup>2</sup>, and a fluence of 5.4 × 10<sup>13</sup> e/cm<sup>2</sup>. Under these conditions the induced radiation defects are predominantly stable cluster-type defects, which is a result of the high electron beam peak intensity. The degradation of the silicon solar cells caused decrease of its parameters, such as the maximum power by more than 40 %. This phenomenon occurs at an electron irradiation fluence more than two orders of magnitude lower than previously reported in the literature for the same effect.</div><div>We propose a hypothesis to explain the open circuit voltage (V<sub>OC</sub>) behavior in irradiated silicon solar cells. Thus, in irradiated solar cells, charge layers are created within the insulator and at the semiconductor-insulator and/or semiconductor-metal interface, which creates electric field - directed oppositely to the field from the p-n junction. It has been shown that the electric field from these charged layers plays a significant role in reducing V<sub>OC</sub> in irradiated solar cells. We suggest that if a controlled charged layer could be created in a solar cell, the electric field direction from which is the same as that of the field from the p-n junction, then the V<sub>OC</sub> could be increased, thus enhancing the efficiency of the solar cells.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"295 ","pages":"Article 113956"},"PeriodicalIF":6.3000,"publicationDate":"2025-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solar Energy Materials and Solar Cells","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927024825005574","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
Abstract
This study investigates the effects of picosecond electron irradiation on the performance parameters of commercial crystalline silicon solar cells fabricated using Passivated Emitter and Rear Contact (PERC) solar technology. The irradiation was performed using electrons with energies up to 3.6 MeV, a pulse current density of jpulse = 200 A/cm2, and a fluence of 5.4 × 1013 e/cm2. Under these conditions the induced radiation defects are predominantly stable cluster-type defects, which is a result of the high electron beam peak intensity. The degradation of the silicon solar cells caused decrease of its parameters, such as the maximum power by more than 40 %. This phenomenon occurs at an electron irradiation fluence more than two orders of magnitude lower than previously reported in the literature for the same effect.
We propose a hypothesis to explain the open circuit voltage (VOC) behavior in irradiated silicon solar cells. Thus, in irradiated solar cells, charge layers are created within the insulator and at the semiconductor-insulator and/or semiconductor-metal interface, which creates electric field - directed oppositely to the field from the p-n junction. It has been shown that the electric field from these charged layers plays a significant role in reducing VOC in irradiated solar cells. We suggest that if a controlled charged layer could be created in a solar cell, the electric field direction from which is the same as that of the field from the p-n junction, then the VOC could be increased, thus enhancing the efficiency of the solar cells.
期刊介绍:
Solar Energy Materials & Solar Cells is intended as a vehicle for the dissemination of research results on materials science and technology related to photovoltaic, photothermal and photoelectrochemical solar energy conversion. Materials science is taken in the broadest possible sense and encompasses physics, chemistry, optics, materials fabrication and analysis for all types of materials.