MXene/PANI/SnO2 electrochemical sensor for the determination of 4-aminophenol

IF 5.3 2区 化学 Q1 CHEMISTRY, ANALYTICAL
Jing Chen, Wenli Xue, Yaqin Shi, Wenjing Liu, Rongfang Ma
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引用次数: 0

Abstract

An electrochemical sensor based on MXene/PANI/SnO2 nanomaterials was developed for the detection of 4-aminophenol (4-AP). In situ oxidative growth of PANI on the MXene surface effectively hindered the stacking of the lamellae and increased the specific surface area of the composites. Further complexation of tin dioxide with swelling properties of the structure provided adsorption and catalytic sites for 4-AP. The prepared electrochemical sensor displayed good Linearity in the concentration range 0.50 ~ 115.38 µM and low detection limit (LOD = 0.19 µM). The sensor also had good reproducibility and stability. The MXene/PANI/SnO2/GCE sensor was applied to the determination of tablets and Yellow River water, and expressed high recoveries and low relative standard deviations.

Graphical Abstract

MXene/PANI/SnO2电化学传感器测定4-氨基酚
研制了一种基于MXene/PANI/SnO2纳米材料的4-氨基酚(4-AP)电化学传感器。聚苯胺在MXene表面的原位氧化生长有效地阻碍了片层的堆积,增加了复合材料的比表面积。具有膨胀特性的二氧化锡进一步络合为4-AP提供了吸附和催化位点。所制备的电化学传感器在0.50 ~ 115.38µM的浓度范围内线性良好,检出限低(LOD = 0.19µM)。该传感器具有良好的重现性和稳定性。将MXene/PANI/SnO2/GCE传感器应用于片剂和黄河水的含量测定,具有回收率高、相对标准偏差低的特点。图形抽象
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来源期刊
Microchimica Acta
Microchimica Acta 化学-分析化学
CiteScore
9.80
自引率
5.30%
发文量
410
审稿时长
2.7 months
期刊介绍: As a peer-reviewed journal for analytical sciences and technologies on the micro- and nanoscale, Microchimica Acta has established itself as a premier forum for truly novel approaches in chemical and biochemical analysis. Coverage includes methods and devices that provide expedient solutions to the most contemporary demands in this area. Examples are point-of-care technologies, wearable (bio)sensors, in-vivo-monitoring, micro/nanomotors and materials based on synthetic biology as well as biomedical imaging and targeting.
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